Probing of Structural Phase Transitions in Barium Titanate Modified Sodium Niobate using Raman Scattering

TL;DR

This study uses Raman spectroscopy to investigate structural phase transitions in modified sodium niobate with barium titanate, revealing multiple phase changes and confirming previous X-ray diffraction results.

Contribution

It provides detailed Raman spectroscopic evidence of phase transitions in NNBTx, highlighting new insights into the structural evolution with composition.

Findings

Disappearance of antiferroelectric modes at x>0.02 indicating phase transition.

Redistribution of Raman line intensities confirming phase changes.

Consistency of Raman results with previous X-ray diffraction studies.

Abstract

Raman Spectroscopic measurements are carried out to investigate the structural phase transitions as a function of composition in modified sodium niobate [(1-x) NaNbO3-xBaTiO3:NNBTx] for x=0.0 to 0.15 at room temperature. The characteristic antiferroelectric modes at around 93.4 and 123.6cm-1alongwith a mode at 155.5 cm-1were found to disappear across the structural phase transition from antiferroelectric orthorhombic phase (Pbcm) to ferroelectric orthorhombic phase (Pmc21) phase for x>0.02. The redistribution of intensities and positions of the Raman lines in bending (150-350 cm-1) and stretching modes (>550cm-1) on increasing the concentration x>0.05 also confirms the occurrence of another phase transition from ferroelectric orthorhombic phase (Pmc21) to another ferroelectric orthorhombic phase (Amm2) phase across x~0.10.The phase transitions as observed from Raman measurements are consistent with previous x-ray diffraction study.