Heteroepitaxial Thin-Film Growth of a Ternary Nitride Semiconductor CaZn2N2

TL;DR

This paper reports the successful heteroepitaxial growth of CaZn2N2 thin films using plasma-assisted MBE, demonstrating promising optoelectronic properties and establishing a new method for stabilizing this ternary nitride semiconductor.

Contribution

It introduces a novel MBE growth technique for CaZn2N2 films, enabling epitaxial stabilization previously only achieved in bulk form, with detailed growth conditions and electronic properties.

Findings

Optical band gap of ~1.9 eV consistent with bulk

Achieved n- and p-type conduction with low carrier densities

Room temperature mobilities of 4.3 and 0.3 cm2/(Vs) for electrons and holes

Abstract

Zinc-based nitride CaZn2N2 films grown by molecular beam epitaxy (MBE) with a plasma-assisted active nitrogen-radical source are promising candidates of next-generation semiconductors for light-emitting diodes and solar cells. This nitride compound has previously only been synthesized in a bulk form by ultrahigh-pressure synthesis at 5 GPa. Three key factors have been found to enable heteroepitaxial film growth: (i) precise tuning of the individual flux rates of Ca and Zn, (ii) the use of GaN template layers on sapphire c-plane as substrates, and (iii) the application of MBE with an active N-radical source. Because other attempts at physical vapor deposition and thermal annealing processes have not produced CaZn2N2 films of any phase, this rf-plasma-assisted MBE technique represents a promising way to stabilize CaZn2N2 epitaxial films. The estimated optical band gap is ~1.9 eV, which is consistent with the value obtained from bulk samples. By unintentional carrier doping, n- and p-type electronic conductions are attained with low carrier densities of the order of 1013 /cm3. These features represent clear advantages when compared with Zn-based oxide semiconductors, which usually have much higher carrier densities irrespective of their intentionally undoped state. The carrier mobilities at room temperature are 4.3 cm2/(Vs) for electrons and 0.3 cm2/(Vs) for hole carriers, which indicates that transport properties are limited by grain boundary scattering, mainly because of the low-temperature growth at 250 {\deg}C, which realizes a high nitrogen chemical potential.