# Limits to crystallization pressure

## TL;DR

This study introduces a new experimental method to image nano-confined crystallization in calcite, revealing that crystallization pressure causes deformation at pressures below the thermodynamic limit, with implications for materials and Earth sciences.

## Contribution

The paper presents a novel experimental technique and a new model for understanding crystallization pressure and its transition mechanisms, addressing longstanding discrepancies between theory and experiment.

## Key findings

- Displacement by crystallization pressure is arrested below the thermodynamic limit.
- A robust model of disjoining pressure is constructed using experimental data.
- A new mechanism for damage-adhesion transition in crystallization is proposed.

## Abstract

Crystallization pressure drives deformation and damage in monuments, buildings and the Earth's crust. Even though the phenomenon has been known for 170 years there is no agreement between theoretical calculations of the maximum attainable pressure and that found experimentally. We have therefore developed a novel experimental technique to image the nano-confined crystallization process while controlling the pressure and applied it to calcite. The results show that displacement by crystallization pressure is arrested at pressures well below the thermodynamic limit. We use existing molecular dynamics simulations and atomic force microscopy data to construct a robust model of the disjoining pressure in this system and thereby calculate the absolute distance between the surfaces. Based on the high resolution experiments and modelling we formulate a novel mechanism for the transition between damage and adhesion by crystallization that may find application in Earth and materials sciences and in conservation of cultural heritage.