# A systematic TMRT observational study of Galactic $^{12}$C/$^{13}$C ratios from Formaldehyde

## TL;DR

This study measures the $^{12}$C/$^{13}$C ratios in Galactic molecular clouds using formaldehyde lines, revealing a linear relationship with Galactocentric distance and suggesting grain-surface formation of H$_2$CO.

## Contribution

First systematic TMRT observational survey of H$_2$CO and H$_2^{13}$CO lines to determine isotope ratios across the Galaxy, incorporating non-LTE modeling for accurate abundance estimates.

## Key findings

- $^{12}$C/$^{13}$C ratios increase linearly with Galactocentric distance.
- Ratios derived from H$_2$CO agree with other molecules, indicating consistent isotope distributions.
- H$_2$CO likely forms on dust grain mantles rather than in the gas phase.

## Abstract

We present observations of the C-band $1_{10}-1_{11}$ (4.8 GHz) and Ku-band $2_{11}-2_{12}$ (14.5 GHz) K-doublet lines of H$_2$CO and the C-band $1_{10}-1_{11}$ (4.6 GHz) line of H$_2$$^{13}$CO toward a large sample of Galactic molecular clouds, through the Shanghai Tianma 65-m radio telescope (TMRT). Our sample with 112 sources includes strong H$_2$CO sources from the TMRT molecular line survey at C-band and other known H$_2$CO sources. All three lines are detected toward 38 objects (43 radial velocity components) yielding a detection rate of 34\%. Complementary observations of their continuum emission at both C- and Ku-bands were performed. Combining spectral line parameters and continuum data, we calculate the column densities, the optical depths and the isotope ratio H$_2$$^{12}$CO/H$_2$$^{13}$CO for each source. To evaluate photon trapping caused by sometimes significant opacities in the main isotopologue's rotational mm-wave lines connecting our measured K-doublets, and to obtain $^{12}$C/$^{13}$C abundance ratios, we used the RADEX non-LTE model accounting for radiative transfer effects. This implied the use of the new collision rates from \citet{Wiesenfeld2013}. Also implementing distance values from trigonometric parallax measurements for our sources, we obtain a linear fit of $^{12}$C/$^{13}$C = (5.08$\pm$1.10)D$_{GC}$ + (11.86$\pm$6.60), with a correlation coefficient of 0.58. D$_{GC}$ refers to Galactocentric distances. Our $^{12}$C/$^{13}$C ratios agree very well with the ones deduced from CN and C$^{18}$O but are lower than those previously reported on the basis of H$_2$CO, tending to suggest that the bulk of the H$_2$CO in our sources was formed on dust grain mantles and not in the gas phase.

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Source: https://tomesphere.com/paper/1904.04108