Amorphous Intergranular Films Enable the Creation of Bulk Nanocrystalline Cu-Zr with Full Density

TL;DR

This paper demonstrates that amorphous intergranular films can enable the production of dense, bulk nanocrystalline Cu-Zr alloys with stable small grain sizes through strategic consolidation techniques.

Contribution

It introduces a method to create dense bulk nanocrystalline Cu-Zr with stable grain sizes by leveraging amorphous complexion formation during consolidation.

Findings

Achieved 99.8% density in bulk nanocrystalline Cu-Zr.

Produced a grain size of 57 nm with stable microstructure.

Demonstrated the role of amorphous films in densification and grain stability.

Abstract

Nanocrystalline metal alloys show great potential as structural materials, but are often only available in small volumes such as thin films or powders. However, recent research has suggested that dopant segregation and grain boundary structural transitions between states known as complexions can dramatically alter grain size stability and potentially enable activated sintering. In this study, we explore strategic consolidation routes for mechanically alloyed Cu-4 at.% Zr powders to capture the effects of amorphous complexion formation on the densification of bulk nanostructured metals. We observed an increase in density of the consolidated samples which coincides with the formation of amorphous intergranular films. At the same time, the grain size is reasonably stable after exposure to these temperatures. As a result, we are able to produce a bulk nano-grained metal with a grain size of 57 nm and a density of 99.8%, which shows an impressive balance of small grain size and high density using simple consolidation techniques.