# Comment on "Experimental Evidence for a State-Point-Dependent Density-Scaling Exponent of Liquid Dynamics"

## TL;DR

This paper refutes a recent claim that the density-scaling exponent varies with state conditions in a specific liquid, demonstrating instead that it remains constant, aligning with established understanding of simple liquids.

## Contribution

The authors re-measured the pressure dependence of relaxation time in DC704 and showed that the density-scaling exponent is actually state-point independent, correcting previous findings.

## Key findings

- Pressure dependence of relaxation time is linear.
- Density-scaling exponent gamma is constant across conditions.
- Previous results suggesting variability are incorrect.

## Abstract

Recently Sanz et al. [A. Sanz, T. Hecksher, H.W. Hansen, J.C. Dyre, K. Niss, and U.R. Pedersen, Phys. Rev. Lett. 122, 055501 (2019).] reported that the scaling exponent gamma for tetramethyl-tetraphenyl-trisiloxane (DC704) varied with temperature; i.e., was not a material constant. Such a finding is at odds with previously published results on this compound and on more than 100 other liquids and polymers. The result of Sanz et al. comes from their measurement of a pressure dependence of the relaxation time at low temperature that becomes weaker with increasing pressure. Such a result is unphysical and contrary to the behavior of all known liquids. We re-measured this pressure dependence for DC704 and find it to be linear over the studied range. Thus, the conclusion of Sans et al. is incorrect; gamma for DC704 is state-point independent, in accord with other simple liquids and polymers.