# Optimal power and efficiency of single quantum dot heat engines: theory and experiment

## TL;DR

This paper combines theory and experiments to optimize the power and efficiency of quantum dot heat engines, highlighting the role of tunnel couplings and external load, and providing practical guidance for maximizing performance.

## Contribution

It introduces a combined theoretical and experimental approach to optimize quantum dot heat engines, including a simple analytic expression for the optimal load and insights into tunneling effects.

## Key findings

- Good agreement between theory and experiment on optimal load
- Second order tunneling minimally impacts maximum power
- Electron contribution to efficiency is reduced by second order tunneling

## Abstract

Quantum dots (QDs) can serve as near perfect energy filters and are therefore of significant interest for the study of thermoelectric energy conversion close to thermodynamic efficiency limits. Indeed, recent experiments in [Nat. Nano. 13, 920 (2018)] realized a QD heat engine with performance near these limits and in excellent agreement with theoretical predictions. However, these experiments also highlighted a need for more theory to help guide and understand the practical optimization of QD heat engines, in particular regarding the role of tunnel couplings on the performance at maximum power and efficiency for QDs that couple seemingly weakly to electronic reservoirs. Furthermore, these experiments also highlighted the critical role of the external load when optimizing the performance of a QD heat engine in practice. To provide further insight into the operation of these engines we use the Anderson impurity model together with a Master equation approach to perform power and efficiency calculations up to co-tunneling order. This is combined with additional thermoelectric experiments on a QD embedded in a nanowire where the power is measured using two methods. We use the measurements to present an experimental procedure for efficiently finding the external load $R_P$ which should be connected to the engine to optimize power output. Our theoretical estimates of $R_P$ show a good agreement with the experimental results, and we show that second order tunneling processes and non-linear effects have little impact close to maximum power, allowing us to derive a simple analytic expression for $R_P$. In contrast, we find that the electron contribution to the thermoelectric efficiency is significantly reduced by second order tunneling processes, even for rather weak tunnel couplings.