Thioethyl-porphyrazine/Nanocarbon Hybrids for Photoinduced Electron Transfer

TL;DR

This paper reports the design of a novel pyrene-substituted porphyrazine that forms supramolecular hybrids with nanocarbons, demonstrating effective photoinduced electron transfer and potential for optoelectronic applications.

Contribution

It introduces a new pyrene-substituted porphyrazine and explores its assembly with nanocarbons for enhanced photoinduced electron transfer.

Findings

Wide spectral absorption in visible range.

Successful formation of PzPy/nanocarbon hybrids.

Photocurrent generation under visible light irradiation.

Abstract

We designed a novel pyrene-substituted thioethyl-porphyrazine (PzPy) and the formation of supramolecular assembly with nanocarbons demonstrating photoinduced electron transfer ability. As revealed by spectroscopic and electrochemical studies, PzPy displays wide spectral absorption in the visible range, charge separation upon photoexcitation, as well as bandgap and highest occupied/lowest unoccupied molecular orbital (HOMO/LUMO) energy values, matching the key requirements of organic optoelectronic. Moreover, the presence of a pyrene moiety promotes attractive interactions with pi-conjugated systems. In particular, theoretical calculations show that in the PzPy the HOMO and LUMO are localized on different positions of the molecule, i.e., the HOMO on the pyrene moiety and the LUMO on the macrocycle. Therefore, HOMO-LUMO excitation gives rise to a charge separation, preventing excitons recombination. Two kinds of non-covalent hybrid composites are prepared by mixing the PzPy with single wall carbon nanotubes (SWNTs) and graphene nanoflakes (GNFs), respectively, and used for photocurrent generation through charge transfer processes between PzPy and nanocarbons. Photoconduction experiments show photocurrent generation upon visible light irradiation of both PzPy/SWNT and PzPy/GNF composites (0.78 and 0.71 mA/W at 500 nm, respectively), demonstrating their suitability for optoelectronic applications and light harvesting systems.