# A note on the uniqueness result for the inverse Henderson problem

## TL;DR

This paper provides a rigorous proof that the inverse Henderson problem's interaction potential is uniquely determined by the equilibrium pair correlation function in the thermodynamic limit, extending Henderson's original result.

## Contribution

It offers a rigorous proof of the uniqueness of the interaction potential in the inverse Henderson problem for the thermodynamic limit, using Gibbs variational principle.

## Key findings

- Confirmed the uniqueness of the potential in the thermodynamic limit
- Extended Henderson's original result with a rigorous proof
- Utilized Georgii's Gibbs variational principle for the proof

## Abstract

The inverse Henderson problem of statistical mechanics concerns classical particles in continuous space which interact according to a pair potential depending on the distance of the particles. Roughly stated, it asks for the interaction potential given the equilibrium pair correlation function of the system. In 1974 Henderson proved that this potential is uniquely determined in a canonical ensemble and he claimed the same result for the thermodynamical limit of the physical system. Here we provide a rigorous proof of a slightly more general version of the latter statement using Georgii's version of the Gibbs variational principle.