Optimal work-to-work conversion of a nonlinear quantum brownian duet
Matteo Carrega, Maura Sassetti, Ulrich Weiss

TL;DR
This paper investigates the optimal work-to-work conversion in a nonlinear quantum system with two drives, demonstrating conditions for maximizing efficiency, power, and minimizing fluctuations, especially in low-temperature, weak-damping regimes where quantum effects dominate.
Contribution
It introduces a framework for optimizing work-to-work conversion in nonlinear quantum systems, surpassing classical trade-off bounds under specific quantum conditions.
Findings
Simultaneous maximization of efficiency, power, and low fluctuations is possible.
Classical trade-off bounds can be undercut in low-temperature, weak-damping regimes.
Nonlinear driving regimes near power maxima show persistent optimal features.
Abstract
Performances of work-to-work conversion are studied for a dissipative nonlinear quantum system with two isochromatic phase-shifted drives. It is shown that for weak Ohmic damping simultaneous maximization of efficiency with finite power yield and low power fluctuations can be achieved. Optimal performances of these three quantities are accompanied by a shortfall of the trade-off bound recently introduced for classical thermal machines. This bound can be undercut down to zero for sufficiently low temperature and weak dissipation, where the non-Markovian quantum nature dominates. Analytic results are given for linear thermodynamics. These general features can persist in the nonlinear driving regime near to a maximum of the power yield and a minimum of the power fluctuations. This broadens the scope to a new operation field beyond linear response.
Peer Reviews
No public reviews on file for this paper yet. If you reviewed it on a platform where reviews are public (OpenReview, ICLR, NeurIPS, ICML), you can paste yours below so the community can read it here.
Videos
No videos yet. Explain this paper in a talk, walkthrough, or lecture? Add one.
Optimal work-to-work conversion of a nonlinear quantum brownian duet
Matteo Carrega
NEST, Istituto Nanoscienze-CNR and Scuola Normale Superiore, I-56127 Pisa, Italy
Maura Sassetti
Dipartimento di Fisica, Università di Genova, Via Dodecaneso 33, 16146 Genova, Italy
SPIN-CNR, Via Dodecaneso 33, 16146 Genova, Italy
Ulrich Weiss
II. Institut für Theoretische Physik, Universität Stuttgart, D-70550 Stuttgart, Germany
Abstract
Performances of work-to-work conversion are studied for a dissipative nonlinear quantum system with two isochromatic phase-shifted drives. It is shown that for weak Ohmic damping simultaneous maximization of efficiency with finite power yield and low power fluctuations can be achieved. Optimal performances of these three quantities are accompanied by a shortfall of the trade-off bound recently introduced for classical thermal machines. This bound can be undercut down to zero for sufficiently low temperature and weak dissipation, where the non-Markovian quantum nature dominates. Analytic results are given for linear thermodynamics. These general features can persist in the nonlinear driving regime near to a maximum of the power yield and a minimum of the power fluctuations. This broadens the scope to a new operation field beyond linear response.
Introduction. — Major efforts in classical and quantum thermodynamics are directed at strategies to efficiently manipulate and transform varied forms of energy into useful ones seifert12 ; kosloff13 ; benenti17 ; esposito09 ; campisi11 ; levy12 ; carrega15 ; carrega16 ; ludovico14 ; taddei18 ; arrachea19 . Optimal heat to work conversion is a founding principle for a wide range of applications, from industrial processes to biological functionalities, thermoelectricity and photovoltaics benenti17 . The seminal work of Carnot established an upper bound, , for the efficiency of all heat engines. It is argued that this bound is saturated for reversible operation with vanishing power yield benenti17 ; curzon75 ; whitney1 ; whitney2 ; broeck05 ; goychuk13 . This poses a severe restriction, as finite power output is essential for useable thermal machines. However, both efficiency and yield have to be sufficiently large for a well working engine: if is small, a major part of energy is wasted, while low output power would not supply sizeable work in finite time. Various studies focussed on the maximum attainable efficiency at a given finite power yield holubec15 ; ryabov16 ; ma18 ; esposito10 ; cavina17 . General relations linking maximum power, maximum efficiency and minimum dissipation have been derived within linear thermodynamics benenti11 ; proesmans16 ; proesmans16duet ; proesmans17 ; benenti18 . It has been proposed that constraints on efficiency at finite power could be overcome in specific settings, e.g., by breaking time-reversal symmetry benenti11 . Various attempts to get close to Carnot efficiency upon retaining finite power have been made allahverdyan13 ; campisi16 ; holubec17 ; polettini17 , e.g., by suggesting working points near to critical phase transitions campisi16 ; holubec17 . However, these settings are impaired by large power fluctuations, which undermine effective working of the machine holubec17 ; solon18 .
A universal trade-off criterion, a bound constraining these quantities and holding for a wide class of classical Markovian systems operating in the steady state, has been derived barato15 ; shiraishi16 ; horowitz17 ; pietzonka18 ; holubec18 ; shiraishi18 . The bound implies that high power yield, efficiency close to the Carnot value, and small power fluctuations are not compatible. Generalizations of the trade-off bound holding for time-periodic systems have been discussed barato18 ; koyuk18 . Recently, weakening of the trade-off bound has been found in ballistic multi-terminal transport brandner18 and in coherent electron transport through resonant single- and double-dot junctions without agarwalla18 and with electron interactions coherence18 .
It is therefore interesting to study systematically the impact of quantum effects on the trade-off criterion in a key model of quantum transport: a quantum Brownian particle (QBP) moving in a tight-binding (TB) lattice and coupled to a thermal reservoir creating Ohmic friction. With two time-dependent external drives, the system forms a quantum Brownian duet and acts as an iso-thermal work-to work converter. The QBP model has widely varied applications weissbook . It describes, e.g. the current-voltage characteristics of a Josephson junction schoen90 ; andersen13 ; wendin17 , transport of charge through impurities in quantum wires kane92 ; voit , and tunneling of edge currents through constrictions in one-dimensional interacting fermion systems wen90 ; kane95 ; giamarchi2004 ; ferraro14 ; dolcetto16 . The Ohmic spectral coupling entails power laws for the temperature and bias dependence of tunneling rates. This leads for weak damping, e.g., to increasing tunneling with decreasing temperature grabert85 ; fisher85b .
In this Letter we first show within linear thermodynamics and weak tunneling, that the specific Ohmic features make possible to optimize performance upon simultaneous adjustment of large power yield, high efficiency and low power fluctuations. We find that for weak damping the trade-off quantity can fall below the classical bound and even can approach zero, as temperature is decreased and the non-Markovian quantum regime is reached. We also focus on a hitherto mostly disregarded regime beyond linear thermodynamics, in which nonlinear external driving and response prevails. We there discover a parameter regime with sizeable power yield, low power fluctuations and efficiency still close to unity.
Model.— Consider a quantum brownian particle (QBP) in a tight-binding (TB) lattice bilinearly coupled to a thermal bath of harmonic oscillators at inverse temperature . The TB-Hamiltonian is and the bath-plus-coupling term is , where , and is the lattice constant. The spectral bath coupling is leggett87 ; weissbook . In the Ohmic scaling limit we have , where is the dimensionless damping strength. The bare transfer amplitude is adiabatically renormalized by the modes to the dressed amplitude . The QBP model maps inter alia on quasiparticles tunneling through a quantum point contact (QPC) in the fractional quantum Hall (FQH) regime wen90 ; kane95 , whereby corresponds to the fractional filling factor . The weak-damping regime matches up with strong repulsive short-range electron interactions.
Here we study energy in- and output of the QBP under time-periodic drive , where . When the QBP is subjected to two independent drives, , as discussed for a classical setting in Ref. proesmans16duet ; proesmans17 , it can operate as a work-to-work converter. But it will require that the respective work rates or powers, , , can be distinguished. We now choose .
At long times, the power reaches the periodic state , and the mean power is . With the deviation , the power fluctuations are , and the mean power spread is .
Consider now mean power and power fluctuations of the driven QBP. First, we deal with order , which is the leading contribution in the weak-tunneling regime. It describes transport via nearest-neighbor transitions, and single-electron transport in the related fermionic model. We have sm
[TABLE]
with . The functions carry the amplitude factor and the Ohmic bath correlations. They read , and leggett87 ; weissbook ; sassetti92
[TABLE]
When the mean powers have opposite sign, , the QBP entity is acting as work-to-work converter with the positive power being the input, and the negative power being the output or yield seifert12 ; proesmans17 . If is the input and is the yield, the efficiency of the converter is . Optimal performance is characterized by maximal efficiency at given input. However, optimization of the converter should also conform to power fluctuations as low as possible. The latter may be rated with the estimate of relative uncertainty
[TABLE]
It has been argued and proven for a huge class of steady-state heat engines with internal classical states that there is a trade-off between large power, high efficiency and low relative uncertainty, being expressed by the joint bound barato15 ; shiraishi16 ; horowitz17 ; pietzonka18 ; shiraishi18
[TABLE]
If efficiency is close to unity with considerable yield, the bound implies that the power fluctuations are quite large. Conversely, if the bound is broken, simultaneous attainment of maximal efficiency, sizeable yield and low power fluctuations are within reach. This can happen indeed, as shown below.
Work-to-work conversion with two monochromatic drives.— If the frequencies of the two drives would be different, the work rates could clearly be distinguished. But here we choose the same frequency, since otherwise the converter could not operate in the linear regime, as different frequencies would not couple proesmans16 . We put
[TABLE]
Here, the tunable phase shift determines the (time-reversal) asymmetry between the two drives.
The drives (6) can be combined into
[TABLE]
With (6) and (7) the time-averaged powers are found as sm
[TABLE]
with , and is a Bessel function. The mean power fluctuations are found from Eq. (2) as
[TABLE]
The expressions (8) - (9) are exact in the weak-tunneling limit for arbitrary strength of the driving amplitudes and .
As the drives (6) have common frequency, one may question whether the powers (8) and fluctuations (9) can be experimentally distinguished. This is possible, in fact, when the forces (6) are independent, e.g., when they operate spatially separated. A system, which can be mapped on the driven QBP, is a quantum point contact (QPC) in a fractional quantum Hall (FQH) bar wen90 ; kane95 ; dubois2013 ; glattli ; vannucciprl ; ronettiprb with two spatially separated terminals at which the gate voltage drives are applied. The filling factor corresponds to the Ohmic coupling parameter . In such physical implementation, the powers (8), and power fluctuations (9) can be measured individually. The QPC model with mapping on the QBP is discussed in the Supplemental Material sm .
Linear response. —
In the linear response (LR) regime, the dependence of the mean powers on the driving amplitudes and is expressed in terms of the Onsager matrix as . We get from Eqs. (8)
[TABLE]
where , and where
[TABLE]
The functions and bear Ohmic bath correlations. Dependence on , and can be given in analytic form sm . The parameter controls the phase shift of the drive (6). In addition, in the LR regime the power variance becomes sm .
The Onsager matrix conveys the interplay of phase tuning of the driving forces and exchange of energy between bath and QBP. In the limit (), the Onsager matrix is symmetric, and the work-to-work converter operates time-reversal symmetrically. As is lowered, the Onsager matrix gets anti-symmetric admixtures, and time-reversal symmetry is broken. In our setting, this scenario sets in without switching on external magnetic fields benenti11 . In the limit (), the Onsager matrix is antisymmetric. Upon tuning , one moves forth or back between these limiting cases.
For the linear model (12), the maximum output power is at ,
[TABLE]
The condition has two roots, which are F_{1,\pm}=\big{(}1\pm\sqrt{1-P^{\star}}\big{)}\,F_{1,\rm MP} . Correspondingly, efficiency and power fluctuations as functions of have two branches,
[TABLE]
where and . The respective two branches collide at .
The two branches are plotted versus in Fig. 1 for efficiency (left) and power fluctuations (right). The behaviors are qualitatively different for and . The left panel shows that high efficiency can be reached on the (+)-branch when , and on the (-)-branch when . In contrast, low power fluctuations arise only in branch (-) when . Hence high efficiency is compatible with low power fluctuations when , i.e., when the antisymmetric off-diagonal parts of the Onsager matrix outweigh the symmetric ones.
To find out optimum working conditions, we now focus on the maximum efficiency (ME) at notable power yield. The efficiency for fixed is maximal at , where , and is given by
[TABLE]
Fig. 2(a) shows versus for different interaction strength . As is decreased, is strictly increasing. In the asymptotic non-Markovian low temperature regime , in which remark
[TABLE]
the function diverges as for and is a positive constant for . Hence, as , reaches unity in the former, and a value less than unity in the latter case. For , the prefactor of the term in Eq. (18) is . Thus, for weak Ohmic damping, or large repulsive Coulomb interaction in the associated fermionic transport model, the ME efficiency dwells close to unity in a considerably wide temperature range.
Eventually, with the function , the trade-off criterion (5) at takes the concise form sm
[TABLE]
In Fig. 2(b) the quantity is plotted versus for different values of . Since , the curves start out for all K at the value . In the regime , we have , and hence grows linearly with inverse temperature at low temperatures, whereas and become constant in this limit. In contrast, in the range , diverges asymptotically as . Thus, the power grows as , the relative uncertainty drops to zero as , and the quantity varies as in this limit. As a result, diverges in the range , stays flat below for , and drops to zero when is in the range , as . Hence the QBP work converter has optimal performance for weak damping . With decreasing temperature the quantity falls well below the classical bound , and eventually drops to zero, as the non-Markovian quantum regime is reached. Hence large power, high efficiency and small power fluctuations are in fact compatible.
We have investigated the impact of an additional -fold frequency drive in the output, . We found that the behaviors shown in Figs. 1 and 2 change only marginally for . Details are given in Ref. sm .
Nonlinear response. — The above results of the LR regime hold when the driving amplitude is sufficiently small, . For larger , the interplay of nonlinear driving with bath correlations becomes significant, and the ME analysis must start with the original expressions (8) and (9). The ME point is found as numerical root of . With this, numerical nonlinear response (NLR) computation of , , and is straight.
The characteristic behaviors of , , and versus in the NLR are shown in Fig. 3 (a)-(c) for (blue) and (red) for . Clear deviations from the LR behaviors occur in (a), (b), and (c), as is increased. The yield reaches a maximum near for both temperatures. By contrast, the NLR power fluctuations run through a flat minimum located near for and near for and spanning a broad amplitude range. In this area, the work-to-work converter has sizeable power yield with simultaneous low power fluctuations and efficiency still close to unity, only slightly smaller than in LR. This indicates that the NLR regime is a promising field for finding best compromise between large power yield, low power fluctuations and high efficiency. Panel (d) displays the trade-off criterion versus for different values of . Most interestingly, the quantity falls below 2 for below 5.5 and sufficiently low temperature. On the contrary, it consistently stays above 2 for larger and arbitrarily low temperatures. In the former case, the power fluctuations are in the flat minimum of panel (b), thereby facilitating shortfall of the trade-off bound in the NLR.
So far, we have studied mean powers and power dispersion of the QBP converter in order . Contributions of higher order in may become significant at sufficiently low , depending on the parameters of the model. Starting out from the real-time version weissbook of the Coulomb gas representation yuval70 of the perturbative series in , we have calculated the terms of powers and variance numerically. These terms result from direct next-to-nearest-neighbor transitions in the TB lattice and coherent transport of two charges in the associated fermionic transport model. In addition to this, we have approximately taken into account all tunneling contributions of higher order of by summation of partial contributions in each order. The quality of this approximate treatment of the strong tunneling regime has been checked for the point , for which all orders in can be summed exactly sassetti92 ; weissbook . Formidable agreement down to very low temperatures has been found. The conclusions of the numerical analysis are that the higher-order tunneling terms yield marginal contributions up to inverse temperature for , and the above weak-tunneling results are qualitatively correct down to much lower temperatures. Until now, reliable results in the asymptotic low temperature regime are missing. Nevertheless, it is rather unlikely that coherent tunneling transitions across many TB states will spoil the characteristics shown above.
Conclusions — We have studied work-to-work conversion of a quantum Brownian particle in a TB lattice subjected to two isochromatic drives and coupled to a thermal bath with Ohmic spectral density. We have argued that this scenario can be experimentally realized and tested by a two-terminal setup of a fractional quantum Hall bar with a quantum point contact. Analytic results in the linear response regime have been presented for mean power, efficiency, power fluctuations, and the trade-off criterion. It has been shown that optimal performance at weak damping and low temperatures comes along with a clear undercut of the classical trade-off bound. We have also focussed on the performance in the regime of nonlinear response to driving with large amplitudes. It has been found that large power yield with low power fluctuations and with efficiency close to unity can be realized in a wide parameter range of the external drive. This uncloses the hitherto mostly unregarded nonlinear response regime as a promising new operation field for isothermal machines.
Acknowledgements.
We wish to thank Udo Seifert for stimulating discussions. M.C. acknowledges support from the project Quant-Eranet “SuperTop”. M. S. thanks UniGE for financial support.
Appendix A Supplemental Material
Power and power fluctuations
The Hamiltonian of the quantum Brownian particle (QBP) in a TB lattice with lattice spacing , bilinearly coupled to a bath of harmonic oscillators and driven by two time-periodic forces of period , and , is sassetti92 ; weissbook
[TABLE]
where
[TABLE]
Here , and is the tunneling coupling energy of neighboring TB states. The spectral density of the bath coupling is . From now on we put .
The power () for the drive is related to the Brownian particle’s velocity as
[TABLE]
The TB representation of the average position of the Brownian particle is a perturbative series in . It can be written as a grand-canonical sum of a 1D gas of charges with complex interactions , where is the distance of the charge pair sassetti92 ; weissbook ; carrega15 . The complex pair interaction includes all effects of the spectral bath coupling, and is defined as
[TABLE]
For complex time , the equilibrium correlation function is analytic in the strip and satisfies
[TABLE]
In the weak tunneling limit, the position of the quantum Brownian particle at time is
[TABLE]
where
[TABLE]
includes the bath correlations, and is the total bias phase accumulated in the time interval extending from to ,
[TABLE]
At times much larger than the decay time of (indicated by the overbar), the power , is
[TABLE]
The function is a periodic function of with period . The steady-state component of is obtained upon taking the average over the period .
[TABLE]
Consider next the power variance, which is defined as
[TABLE]
where . At long times, we then have
[TABLE]
and with the relation
[TABLE]
From this, the steady-state component is found in order as
[TABLE]
where
[TABLE]
The property (5) leads to the detailed balance relation weissbook
[TABLE]
The Ohmic spectral density of the coupling is , where is the dimensionless coupling strength. Upon including modes above a cut-off frequency in adiabatic approximation, we obtain from Eq. (4) the analytic form
[TABLE]
With the dressed tunneling amplitude , the functions (7) and (15) take in the range the forms
[TABLE]
Brownian duet
Consider mean power and power variance for isochromatic driving with an added multiple frequency term in the output channel, and a phase shift in the input channel,
[TABLE]
With the drive (19), the bias phase can be written as
[TABLE]
where , and . The bias phase factor
[TABLE]
is a periodic function of time . It can be written as the double Fourier series
[TABLE]
where is a Bessel function, and where
[TABLE]
With the Fourier series (22), the time averages in Eqs. (10) and (14) are straightforward, yielding for
[TABLE]
The functions and are defined by single infinite sums, in which the coefficients are products of two -Bessel functions times phase factors. For , we have . Then the sums reduce to individual contributions. These are
[TABLE]
and
[TABLE]
The expressions (24) with (25) and (26) yield the expressions (8) and (9) of the Letter.
Linear response
In linear thermodynamics, the fluxes are linear in the forces, and the powers are quadratic forms of the forces, , where is the Onsager matrix. Expanding the general expression (9) up to terms quadratic in the forces and , and taking the time average, we get
[TABLE]
From this, the Onsager matrix can be extracted as
[TABLE]
For the drive (19), we get
[TABLE]
where , and . The functions and are
[TABLE]
The power variance in steady-state to second order in the force is given by
[TABLE]
Observing the detailed balance relation (16), we finally obtain
[TABLE]
where
[TABLE]
With the function (17), the integrals (32) and (33) can be calculated in analytic form. The resulting expressions are given in terms of Euler’s function as
[TABLE]
The ratio of these functions, , is
[TABLE]
*Maximum output power. —
For the drive (19), the maximum output power or yield is at
[TABLE]
yielding
[TABLE]
The two branches for the efficiency and the relative uncertainty as functions of , resulting from the condition , are
[TABLE]
where
[TABLE]
In the absence of the multiple frequency drive, , these forms reduce to the expressions (13) and (14) of the Letter.
*Maximum efficiency. —
The efficiency is maximal at , where
[TABLE]
It is given by
[TABLE]
The corresponding mean power and power fluctuations are
[TABLE]
With the expressions (45) and (A), the trade-off quantity
[TABLE]
is found in analytic form as
[TABLE]
where . In the absence of the multiple frequency term in the drive , , we have and , and thus the expressions (45) and (48) reduce to the expression (15) and (17) of the Letter.
In the asymptotic low temperature regime , we obtain from (A) and (A)
[TABLE]
and
[TABLE]
Since diverges for , as , whereas , and are temperature-independent in this limit, the qualitative behaviors of and are independent of the coupling parameter . Altogether, the behaviors of efficiency, power fluctuations and trade-off displayed in Figs. 1 and 2 of the Letter change only marginally, when a multiple frequency contribution is added to the base-frequency term in the output .
When the multiple frequency contribution is added in the output channel, as in Eq. (19), the element of the Onsager matrix is modified by a factor . If instead we had added a multiple frequency term in the input channel , the element of the Onsager matrix, would be changed by a factor . With the argumentation similar to that below Eq. (50), one would find again that efficiency, power fluctuations, and trade-off change only marginally, when a multiple frequency contribution is added to the base-frequency term in the input .
**Mapping with quasiparticle tunneling through
a quantum point contact (QPC) in a FQH system**
Consider a fractional quantum Hall (FQH) bar (see Fig. 1) with Laughlin filling factor ) described in hydrodynamical formulation wen90 by the model Hamiltonian
[TABLE]
[TABLE]
Here, describes the chiral edge states with propagation direction and velocity in terms of bosonic fields . The term represents capacitive coupling of the densities with two voltage gates acting separately on the right and left moving excitations. The step functions describes the case of very long contacts, which is in accordance with standard experimental setups dubois2013 ; glattli . The contacts are separated by distance . Weak backscattering transfer of quasiparticles between the two edges at the QPC located at is described by the tunneling term . Here, is the quasiparticle annihilation operator, is a cut-off length, a Klein factor, and is the Fermi momentum.
In the absence of the QPC, the currents at the terminals placed at are the right/left moving edge currents,
[TABLE]
where is the universal quantum of conductance in the FQH regime. In the presence of the QPC, these current are modified by the backscattering current of the quasiparticles as
[TABLE]
and the associated powers are
[TABLE]
The powers resulting from backscattering alone are
[TABLE]
Following the analysis set out in Refs. vannucciprl ; ronettiprb , the backscattering current for weak quasiparticle tunneling is found as
[TABLE]
where , and is the connected Green’s function of the quasiparticle field at , . Upon equating the filling factor with the Ohmic damping parameter , and the length with , there directly holds in the scaling limit the correspondence
[TABLE]
where is the Ohmic bath correlation function (17). With the correspondences , , , and with , the mean backscattering current is found from Eq. (57) as
[TABLE]
Hence, time average of the powers given in Eq. (56) with the backscattering current (59) directly yields the expression (10) for , which coincides with the expression (1) of the Letter. In accordance with this, the power fluctuation resulting from backscattering are found as given in Eq. (14) with (15), and in Eq. (2) of the Letter. Thus we have demonstrated complete correspondence in the scaling limit of the above QPC with the QBP system. The virtue of the QPC geometry is, that powers running through the left- and right terminals resulting from the backscattering current, and the associated power fluctuations, can be measured individually.
The reference list from the paper itself. Each links out to its DOI / PubMed record.
- 1(1) U. Seifert, Rep. Prog. Phys. 75 , 126001 (2012).
- 2(2) R. Kosloff, Entropy 15 , 2100 (2013).
- 3(3) G. Benenti, G. Casati, K. Saito, and R. S. Whitney, Phys. Rep. 694 , 1 (2017).
- 4(4) M. Esposito, U. Harbola, and S. Mukamel, Rev. Mod. Phys. 81 , 1665 (2009).
- 5(5) M. Campisi, P. Hänggi, and P. Talkner, Rev. Mod. Phys. 83 , 771 (2011).
- 6(6) A. Levy, R. Alicki, and R. Kosloff, Phys. Rev. E 85 , 061126 (2012).
- 7(7) M. Carrega, P. Solinas, A. Braggio, M. Sassetti, and U. Weiss, New J. Phys. 17 , 045030 (2015).
- 8(8) M. Carrega, P. Solinas, M. Sassetti, and U. Weiss, Phys. Rev. Lett. 116 , 240403 (2016).
