# Tracking the connection between disorder and energy landscape in glasses using geologically hyperaged amber

## TL;DR

This study uses geologically hyperaged amber to explore how natural aging affects the energy landscape and vibrational properties of glasses, revealing densification, reduced disorder, and changes in elastic correlations.

## Contribution

It provides the first direct link between natural aging in amber and modifications in the energy landscape and vibrational dynamics of glasses.

## Key findings

- Hyperaging depletes vibrational density of states in the THz region.
- Aging causes densification with structural differences from hydrostatic compression.
- Elastic matrix becomes less disordered and more correlated with aging.

## Abstract

Fossil amber offers the unique opportunity of investigating an amorphous material which has been exploring its energy landscape for more than 110 Myears of natural aging. By applying different x-ray scattering methods to amber before and after annealing the sample to erase its thermal history, we identify a link between the potential energy landscape and the structural and vibrational properties of glasses. We find that hyperaging induces a depletion of the vibrational density of states in the THz region, also ruling the sound dispersion and attenuation properties of the corresponding acoustic waves. Critically, this is accompanied by a densification with structural implications different in nature from that caused by hydrostatic compression. Our results, rationalized within the framework of fluctuating elasticity theory, reveal how upon approaching the bottom of the potential energy landscape (9% decrease in the fictive temperature $T_f$) the elastic matrix becomes increasingly less disordered (6%) and longer-range correlated (22%).