Unfolding of phases and multicritical points in the Classical Anisotropic van Hemmen Spin Glass Model with Random Field
S. G. Magalhaes, I. C. Berger, R. Erichsen Jr

TL;DR
This paper investigates how random fields and interactions in a 3-state spin glass model lead to the emergence of multiple distinct spin glass phases and multicritical points, revealing complex phase behavior.
Contribution
It introduces a detailed analysis of phase unfolding and multicritical points in a 3-state van Hemmen spin glass model with random fields, highlighting new phase structures.
Findings
Two distinct spin glass phases emerge under strong random fields.
Four separate phases including a mixed phase are identified.
Multiple triple and multicritical points are found in the phase diagram.
Abstract
We study magnetic properties of the 3-state spin ( and ) spin glass (SG) van Hemmen model with ferromagnetic interaction under a random field (RF). The RF follows a bimodal distribution The combined effect of the crystal field and the special type of on-site random interaction of the van Hemmen model engenders the unfolding of the SG phases for strong enough RF, i. e., instead of one SG phase, we found two SG phases. Moreover, as is finite, there is also the unfolding of the mixed phase (with the SG order parameter and the spontaneous magnetization simultaneously finite) in four distinct phases. The emergence of these new phases separated by first and second order line transitions produces a multiplication of triple and multicritical points.
| Phases | ||||
|---|---|---|---|---|
| PM | 0 | 0 | 1 | |
| SG1 | 0 | 1/2 | 1 | () |
| SG1 | 0 | 1/2 | 1/2 | () |
| SG2 | 0 | 1/4 | 3/4 | () |
| SG2 | 0 | 1/4 | 1/4 | () |
| NM | 0 | 0 | 0 |
| Phases | ||||
|---|---|---|---|---|
| PM | 0 | 0 | 1 | |
| M1 | 1/2 | 1/2 | 1 | |
| M2 | 1/4 | 1/2 | 3/4 | |
| M3 | 1/4 | 1/4 | 1/2 | |
| M4 | 3/8 | 3/8 | 5/8 | |
| SG1 | 0 | 1/2 | 1 | () |
| SG1 | 0 | 1/2 | 1/2 | () |
| SG2 | 0 | 1/4 | 3/4 | () |
| SG2 | 0 | 1/4 | 1/4 | () |
| NM | 0 | 0 | 0 |
| Phases | ||||
|---|---|---|---|---|
| FE1 | 1 | 0 | 1 | |
| FE2 | 1/2 | 0 | 1/2 | |
| NM | 0 | 0 | 0 | |
| PM | 0 | 0 | 1 |
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Unfolding of phases and multicritical points
in the Classical Anisotropic van Hemmen Spin Glass Model with Random Field
S. G. Magalhaes
I. C. Berger, R. Erichsen Jr
Instituto de Física, Universidade Federal do Rio Grande do Sul, Porto Alegre, RS, Brazil
Abstract
We study magnetic properties of the 3-state spin ( and ) spin glass (SG) van Hemmen model with ferromagnetic interaction under a random field (RF). The RF follows a bimodal distribution The combined effect of the crystal field and the special type of on-site random interaction of the van Hemmen model engenders the unfolding of the SG phases for strong enough RF, i. e., instead of one SG phase, we found two SG phases. Moreover, as is finite, there is also the unfolding of the mixed phase (with the SG order parameter and the spontaneous magnetization simultaneously finite) in four distinct phases. The emergence of these new phases separated by first and second order line transitions produces a multiplication of triple and multicritical points.
1 Introduction
Disorder effects in magnetic systems with localized spins considering random interaction, frustration and random fields are permanent sources of challenging issues. The simultaneous combination of these complex examples of disorder does exist in real systems. It can be found in FexZn1-xF2 and FexMg1-xCl2 compounds [1]. More recently, spin glass and RF have been also suggested to exist in the diluted Ising-like dipolar ferromagnetic compound LiHoxY1-xF4 [2]. The existence of real systems with the combined presence of a spin glass (SG) phase and random field (RF) makes its description a quite relevant problem in the disordered magnetism with localized spins (see, for instance, Ref. [3]).
Such description has several obstacles. One of them concerns the use of replica method. In particular, the dispute about the existence of a replica symmetry breaking (RSB) in a Ising SG model as predicted by Parisi [4]. The crucial validation of this scenario would be the existence of the de Almeida-Thouless line [5]. This existence is still currently disputed by simulational techniques or even experimentally [6]. In addition, for 3-state disordered spins models, the replica method presents others difficulties. These models are known by displaying tricritical points and, therefore, a first order line transition whose location is a complicated task within the replica method. For example, it is known that in the Gathak-Sherrington model at mean field level [7], the proper location of the first order line transition is far from obvious since the stability requirements do not provide proper guidance to select correctly the SG solution [8]. Indeed, the presence of a RF complicates the situation since the first order phase transition line is much affected by the RF [9, 10]. Another aspect that should be remarked is that the RF field induces the replica symmetric SG order parameter which becomes finite at any temperature. As a consequence, it is strictly necessary to find RSB SG solutions of the order parameters [11] which makes even more complicated the location of the first order line transition. That situation enforces the necessity to work with disordered spin models in the presence of RF which avoids the replica method.
We present in this work an analysis of the combined effect of random couplings and random fields in the 3-state spin ( and ) van Hemmen model with a crystal field , the so called anisotropic van Hemmen spin glass (AvHSG) model [12, 13]. This on site-disorder model was introduced as an exactly solvable model suitable to describe metallic SG without the use of the replica method. It has both fundamental ingredients for the SG phase, i. e., disorder and frustration. Although its infinite-range version does not present a complex free energy landscape with a large number of local minima [14], the van Hemmen model can account for several static properties of real SG systems. Another important aspect is that this model displays naturally mixed phases if a ferromagnetic interaction is also present. In this mixed phase the SG order parameter and the spontaneous magnetization are simultaneously finite. Its existence is deeply related to the special type of on-site random interaction of the van Hemmen model which are given as a product of local random variables [12, 13]. In the AvHSG model the number of sites with spins magnetically actives can no longer coincides with the number of site lattices .
The combined effects of and the uniform field are well illustrated in a previous study of the AvHGS model performed by de Almeida and Moreira [15]. At , for small and , these authors found the usual spin glass phase with spin glass order parameter and magnetization , as expected. Interestingly, for large and frustration is still favored. As consequence, there is the emergence of a new special type of mixed phase with (induced by ) and SG order parameter . Moreover, at , the phase transition lines between paramagnetism (PM), SG and this mixed phase are all first order. At finite temperature, the phase transition lines are first and second order. As consequence, there are ordered critical and tricritical points.
The scenario described previously arises the question which are the consequences if the uniform field is replaced by a RF? While for small RF and , one can expect the presence of the usual SG phase (as found in the case with uniform field), it is far from obvious what is the scenario when RF and are large. As result, we anticipate that the combination of effects coming from RF and is responsible by the unfolding of the SG phase in two. To be precise, at , we find two solutions for the SG order parameter instead of one, i. e., the usual one for small RF and and a new one for large RF and . The phases corresponding to each solution have genuine phase transitions between them. Furthermore, since we also analyse the AvHSG model with a presence of a ferromagnetic interaction, one might expect that the unfolding happens not only with SG phase, but also with mixed phase. As consequence, one can also expect a complicated scenario of reentrant transitions between paramagnetic, SG and mixed phases. At , the transitions between these several phases can be not only first order but also second. Thus, one can have the multiplication of multicritical points.
It should be remarked the role of RF or when acting alone. For instance, It is well known that tends to destroy any magnetic long range order by favoring states . In its turn, previous results on the Ising van Hemmen model with RF [16] show that the RF tends to suppress the SG phase. Therefore, it is quite clear that neither the RF nor the D acting alone can produce the unfolding of phase obtained in our work. Lastly, it is worth mentioning a recent work by Morais et al [17] using a random crystal field (instead of a RF) following a bimodal distribution with a fraction of the spins without the influence of the crystal field and fraction under the influence of . Their results show that when increases, the SG phase appears even for large .
This paper is structured as follows. In Section II, we discuss the model and give details of the analytic calculations in the anisotropic van Hemmen model with RF in order to obtain the order parameters. Our numerical solutions for the order parameters are summarized in phase diagrams which are displayed in Section III. The conclusion is presented in Section IV.
2 Model
The model is given by the Hamiltonian
[TABLE]
where the spins can assume values . In the first term, represents the uniform ferromagnetic interaction while is the anisotropic crystal field. The disordered interaction is given by
[TABLE]
in which and are independents random variables following the bimodal distribution
[TABLE]
The random field is also distributed according to the bimodal distribution:
[TABLE]
The partition function can be written as
[TABLE]
with ( is the temperature). The quadratic terms in Eq. (5) can be linearized by the Gaussian identity , introducing the SG order parameters
[TABLE]
and magnetization
[TABLE]
At the minimum free energy one has that . Thereby, the free energy per spin is given as
[TABLE]
with . The equations for magnetization and spin glass order parameter follow from the saddle point equations: and , respectively. Thus
[TABLE]
and
[TABLE]
The symbol represents the averages on , and which are performed using the distributions given in Eqs. (3)-(4).
It is also important to investigate the average magnetic occupation. Therefore, we also calculated which gives
[TABLE]
In the context of the present work, indicates not only whether the spin state on the sites are magnetically active to interact with other spins but also whether they are coupled with the RF.
3 Results
In this section, we present and discuss phase diagrams for: (i) which does give ; (ii) which can give . Therefore, in general terms, one can distinguish four phases: (i) SG with and ; (ii) ferromagnetic with and ; (iii) paramagnetic with and and (iv) the mixed phase with and . As we shall discuss below, these phases are unfolded into distinct thermodynamic phases with different numerical values for , and . We also remark that the crystal field , and are given in units of (see Eq. (2)).
3.1 Phase diagrams with
3.1.1 Temperature
Firstly, it should be remarked that the RF prevents any induced magnetization. Therefore, for , it is ruled out any finite induced or spontaneous magnetization.
We display in Fig (1) the possible ground states in the phase diagram vs . In the Table I are shown the respective numerical values of and . There are two regions to be considered initially, large and small and vice-versa. In the first region, for large and small , it is found the NM phase while in the second one, for small and large , it is found the PM phase. The NM and PM phases have and , respectively. In the region NM, since , most of the spin states in the sites are magnetically non-actives preventing, therefore, any spin glass ordering. In contrast, in the PM phase most of the spin states are magnetically active. However, there is no spin glass solution which indicates that for , the RF also prevents any spin glass ordering. Thus, both situations have but with distinct values for . The situation is utterly changed for small and (, and ). There, one can expect the existence of the usual spin glass ordering found in the AvHSG model (SG1 in the Fig. (1) with ) since there are conditions for the dominance of a spin glass ordering provided by the random interaction of the AvHSG model. Much less obvious is the existence of a second spin glass ordering (SG2 in the Fig. (1) with ). The mechanism for the onset of SG2 phase is uncommon. For a certain combination of large and ( and ), the dilution of magnetically active sites favored by competes with the disordered site activation provided by the increase of and creates again the dominance of a spin glass ordering. Therefore, the SG phase is unfolded in two distinct phases SG1 and SG2.
We remark another important difference between SG1 and SG2 phases as compared with NM and PM phases. For instance, in the NM and PM phases, the magnetic occupation does not depend on . In contrast, inside the SG1 and SG2 phases, the behavior of is determined by the relationship as can be seen in Table
- As consequence, the dotted line in Fig. (1) represents a crossover line separating regions with distinct values of inside the same phase (SG1 or SG2) which reflects a fine balance which determines distinct amounts of magnetically active sites inside SG1 and SG2 phases above and below the line . It should be mentioned that the boundaries lines of the four phases discussed above Fig. (1) are first order ones. As consequence, there are two triple points in the phase diagram.
3.1.2 Temperature
The effects of temperature increase the complexity of the problem bringing the presence of tricritical and ordered critical points. The sequence of phase diagrams displayed in the Figs. (2)-(4) has constant , and , respectively. We point out that the phase diagrams have topology similar with those ones found in Blume-Capel model with a RF given in Ref. [19].
The values of chosen above select three distinct types which can be organized in terms of the presence of tricritical and ordered critical points. It is well known that, at mean field level, one can find in a 3-state spins models the presence of tricritical points which can have two sources: (i) due to the favoring of states at lower temperature as increases (for instance, a the Blume-Capel model [18]) and ; (ii) reminiscent of Ising limit () of the AvHSG model with bimodal RF. We named the tricritical points related with the scenario discussed in (i) and (ii) as TC1 and TC2, respectively.
The first type of phase diagram can be seen in Fig. (2). At lower temperature, SG1 and SG2 phases are separated by a first order line transition ending at an ordered critical point. Then, SG1 and SG2 phases become identical. Consequently, there is a second order phase line transition separating the PM phase from the spin glass phase. This second order line becomes a first order one at the TC2 point. The second type of phase diagram is displayed in Fig. (3). Besides the presence of an ordered critical point and the TC2 point, there is also the emergence of the TC1 point for smaller . Other interesting aspect is that the paramagnetic phase is splitted into NM and PM phases. The presence of NM phase for smaller suggests that the TC1 point can be related with the phase transition between the NM (instead of PM) and any spin glass phase. This relationship is well illustrated in Fig. (4). In the phase diagram shown in that figure, the only remaining ordered phase is SG2 existing in a dome-shaped region. Thus, there is no longer an ordered critical point. The phase transition line between the SG2 phase and NM for smaller and, then, PM phases for larger present TC1 and TC2 points. Their location were also checked by the expansion of free energy in terms of the SG order parameter in the Appendix.
3.2 Phase diagrams with
3.2.1 Temperature
The presence of ferromagnetic interaction brings the possibility of finite spontaneous magnetization and, as consequence, the arising of mixed or ferromagnetic phases. In order to find such phases, we choose and .
In the case , Table II provides the numerical values for the , and corresponding to each phase in Fig. (5). The phases SG1, SG2, NM and PM have the same numerical values for these quantities already displayed in Table I. In addition, there is the emergence of mixed phases. It is well established the existence of a mixed phase in the AvHSG model without a RF. Nevertheless, our results show that not only part of the spin glass phase, which is already unfolded, is replaced by a mixed one but also the mixed phase is unfolded in four distinct phases (M1, M2, M3 and M4 in Fig. (5)) with first order transition separating them and the SG1 and SG2 phases. Each one, M1, M2, M3 or M4 have a different combination of numerical values for , and (see Table II). For instance, inside of the SG1 phase there is the emergence of the M1 phase for very small values of and (, and ) which corresponds to the usual mixed phase of the AvHSG model (, and ). However, the emergence of M2, M3 and M4 is again not obvious. For these mixed phases, there is a fine balance of mechanisms driven by the energy scales , and (given in units of ) within the region where the phases SG1 and SG2 are initially located. Then, inside the SG1 phase appears also the M2 phase ( and ). Inside the SG2 appears the M3 phase ( and ). The M4 phase appears between M2 and M3 phases ( and ). It should be also stressed that this fine balance affects also the average magnetic occupation per site with the sequence of jumps as can be seen in Table 2 from M1 to M4. It should be mentioned that due to the number of phases with first order transitions between them, one has 8 triple points in Fig. (5). Another aspect to be mentioned is that for some fixed values of , by varying (or vice-versa), the SG1 and SG2 phases are reentrant.
In the case there is no longer spin glass or mixed phases which are entirely replaced by a ferromagnetic one. This phase is also unfolded depending on and . The corresponding FE1 and FE2 phases have and given in Table III. That case recovers entirely the results obtained for the Blume-Capel model with RF given in Ref. [19].
3.2.2 Temperature
In this section we discuss only the case , since the case reproduces exactly the results obtained in Ref. [19] at finite temperature.
In Figs (6)-(11) are shown phase diagrams vs with , , , , and , respectively. These choices for values of allow to display the most interesting types of phase diagrams in terms of multicritical points. These phase diagrams are even more complex as those ones displayed in Section 3.2.1 since the number and the variety of multicritical points are enhanced.
As a whole, the features observed in Fig. 6 are preserved in Figs. (7 - 11), but there are additional features that deserve discussion. These figures are representative examples of vs. phase diagrams that are observed in the interval , where phases SG1 and SG2 coexist at low temperature. The first-order line between them ends in a critical point. It moves in the diagram from the right, like in Fig. (7), to the left, like in Fig. (10), as increases. Figure (7) corresponds to . The dome shaped region is a M2 phase, at the left of the first-order line. Figure (10) corresponds to . The dome shaped region is a M3 phase, at the right of the first-order line. Figures (8) and (9), for and , respectively, show the interesting situation where the first-order line goes through the dome shaped region, giving rise to the appearance of the M4 subphase. In Fig. (8) M4 appears between M2 and M3. Consequently, this figure shows a triple point intersecting two second-order lines. The triple point joins first-order lines that separate phases with three distinct , values. These are: in phases M2 and SG1; in phase M4; in phases M3 and SG2. The second order line separates the continuous transition from , in phases M2 and M3 to , in phases SG1 and SG2. In Fig. (9) M2 is absent, and the phase diagram shows a triple point between SG1, SG2 and M4 and a critical endpoint where M4 makes first-order transitions with SG2 and M3 and M3 makes a second-order transition to SG2.
In Fig. (11), the situation is completely changed. According to Fig. (5), there SG1 phase is no longer present at if and, consequently it should not be found at finite . There is only the SG2 phase which occupies a dome-shaped spin glass region. Similarly to the phase diagram shown in Fig. (4), the paramagnetic phase is splitted in NM (smaller ) and PM (larger ) ones. Consequently, one has again TC1 and TC2 points. Furthermore, at lower temperature there is a reentrant M3 phase occupying a dome-shaped region inside the SG2 phase. In the transition line between SG2 phase to M3 one also has two tricritical points.
4 Conclusions
We studied the 3-state van Hemmen spin glass model in the presence of a bimodal RF, in a mean-field approximation, in three different scenarios: i) in the absence of uniform ferromagnetic interaction (), where only spin glass, paramagnetic and non-magnetic phases are present; ii) in the presence of a moderate uniform ferromagnetic interaction () where, in addition to the phases mentioned above, mixed phases were observed; iii) in the presence of a strong uniform ferromagnetic interaction (), we found ferromagnetic phases, besides the paramagnetic and non-magnetic phases. For this particular case, the phase diagrams reproduce the results found for the Blume-Capel model with a random field given in Ref. [19]. It worths to remember that non-magnetic and paramagnetic phases differ only in the occupation per site .
For , the zero-temperature vs. phase diagram displays the unfolding of SG phase in two distinct phases labeled SG1 and SG2. Such unfolding appears as a fine balance between the RF (that favors active states ) and the crystal field (that favors ). Furthermore, in both SG1 and SG2 the occupation per site changes discontinuously over the diagonal at . For finite temperature, besides one or two (for the dome shaped SG region) tricritical points, there is also the emergence of a critical point related to the unfolding of the SG phase.
Far more interesting is the situation for , with the appearing of several mixed phases and an unusual scenario of triple points and multicritical points. The zero temperature vs. phase diagram shows four mixed phases, labeled M1 to M4, located near the diagonal , inside the two spin glass phases. By fixing we obtain several vs. phase diagrams, where the mixed phases appear as a dome shaped region inside a spin glass phase. The most intriguing ones are those where the mixed phase dome interacts with the first-order line between SG1 and SG2, at low temperature, giving rise or to a triple point intersecting two critical lines or a triple point close to a critical endpoint.
Next, we briefly discuss the contribution of our work as compared with previous studies of magnetic models with RF. In fact, the results obtained in the Blume-Capel model [19] or in the Ising van Hemmen model [16] both with RF can be considered limit situations of our model. The first case corresponds to the situation where while the second one corresponds to . Moreover, the AvHSG model with uniform field [15] is also contained in our model if the RF distribution in Eq. 4 is generalized as taking the limit .
We enphasize that the most important result of our work is to show how the combined effects of and RF can create conditions to stabilize SG and mixed phases. That is far from obvious, since the effects of D and RF taken individually tends to suppress these phases (at least, at mean field level). Particularly, this result leads to a complicate scenario of reentrant phases when the RF increases. Surely, there is a subtil mechanism. At , for small D and RF, it is quite clear that the random interaction is the dominant energy scale. Nevertheless, when RF and increase, they do compete, but mainly to stablish an average magnetic occupation which is neither (spins totally active) nor (spins totally non-active). The main consequence is that there are still spins available () to interact via random interaction and, eventually, via ferromagnetic interaction as well. That is the reason because SG and the mixed phases stabilise but with order parameter smaller than the corresponding values with small RF and . We believe that this mechanism is independent of any specific choice of random field distribution. It should be remarked that there is one common aspect of our result with those ones found in the Ref. [19]. That is the unfolding of phases as well as the proliferation of multicritical points. As demonstrated in our work, we can recover entirely the results of Ref. [19] when the ferromagnetic interaction overcomes the random one. Indeed, what we are demonstrating is how those results can develop as long as disordered interaction is being added.
Although our results refer a particular model, we expect that our results can shed light in problems containing the interplay among random interaction and field, ferromagnetic interaction and crystal field. A possible physical realization of such scenario might be found, for instance, in martensitic alloys. In these systems, it has been stablished the existence of strain glasses which is the analogue of SG concerning lattice distortions. In this glassy phase, there are local random configurations of lattice distortion [22, 23]. Finally, we would like to remark that our study does not aim to be exhaustive. So, it is not excluded the possibility for more complicated features, in terms of multicritical points, for different values of or . On other hand, we remark that we are doing a mean field theory. The existence of some multicritical points may be related with this level of description (see, for instance, [20, 21]).
Acknowledgments
The present study was supported by the brazilian agencies Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) and CAPES. The authors acknowledge Profs. M. C. Barbosa and J. J. Arenzon for useful discussions.
5 Appendix
The tricritical points TC1 and TC2 are obtained from the expansion of the free energy (see Eq. (8)). Therefore:
[TABLE]
where and
[TABLE]
[TABLE]
[TABLE]
with , and . To obtain the second order line transition, we use and . The tricritical points are located when , and .
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