# Phonon polaritonics in two-dimensional materials

## TL;DR

This paper derives a first-principles model for phonon polaritons in 2D materials, revealing their properties, confinement, and interaction with emitters, with implications for nanoscale control and hybrid states.

## Contribution

It provides a universal conductivity expression for 2D phonon polaritons and analyzes their confinement, losses, and strong coupling with emitters in monolayer materials.

## Key findings

- Phonon polaritons in 2D are simply the LO phonons of the system.
- High confinement and reasonable propagation quality factors can coexist.
- External emitters can strongly couple with 2D phonon polaritons, enabling hybrid states.

## Abstract

Extreme confinement of electromagnetic energy by phonon polaritons holds the promise of strong and new forms of control over the dynamics of matter. To bring such control to the atomic-scale limit, it is important to consider phonon polaritons in two-dimensional (2D) systems. Recent studies have pointed out that in 2D, splitting between longitudinal and transverse optical (LO and TO) phonons is absent at the $\Gamma$ point, even for polar materials. Does this lack of LO--TO splitting imply the absence of a phonon polariton in polar monolayers? Here, we derive a first-principles expression for the conductivity of a polar monolayer specified by the wavevector-dependent LO and TO phonon dispersions. In the long-wavelength (local) limit, we find a universal form for the conductivity in terms of the LO phonon frequency at the $\Gamma$ point, its lifetime, and the group velocity of the LO phonon. Our analysis reveals that the phonon polariton of 2D is simply the LO phonon of the 2D system. For the specific example of hexagonal boron nitride (hBN), we estimate the confinement and propagation losses of the LO phonons, finding that high confinement and reasonable propagation quality factors coincide in regions which may be difficult to detect with current near-field optical microscopy techniques. Finally, we study the interaction of external emitters with two-dimensional hBN nanostructures, finding extreme enhancement of spontaneous emission due to coupling with localized 2D phonon polaritons, and the possibility of multi-mode strong and ultra-strong coupling between an external emitter and hBN phonons. This may lead to the design of new hybrid states of electrons and phonons based on strong coupling.