# Berry-phase effects in dipole density and Mott relation

## TL;DR

This paper develops a unified semiclassical framework for thermoelectric responses of various observables in periodic crystals, incorporating Berry-phase effects and generalizing the Mott relation to multiple physical quantities.

## Contribution

It introduces a comprehensive semiclassical theory that includes Berry-phase effects for thermoelectric responses of any observable in crystals, extending the Mott relation and generalizing the concept of dipole density.

## Key findings

- Established Einstein and Mott relations with Berry-phase effects
- Generalized magnetization current to various observables
- Identified the role of dipole density including Berry-phase corrections

## Abstract

We provide a unified semiclassical theory for thermoelectric responses of any observable represented by an operator $\hat{\boldsymbol{\theta}}$ that is well-defined in periodic crystals. The Einstein and Mott relations are established generally, in the presence of Berry-phase effects, for various physical realizations of $\hat{\boldsymbol{\theta}}$ in electronic systems, including the familiar case of the electric current as well as the currently controversial cases of the spin polarization and spin current. The magnetization current, which has been proven indispensable in the thermoelectric response of electric current, is generalized to the cases of various $\hat{\boldsymbol{\theta}}$. In our theory the dipole density of a physical quantity emerges and plays a vital role, which contains not only the statistical sum of the dipole moment of $\hat{\boldsymbol{\theta}}$ but also a Berry-phase correction.