Light-by-light-scattering contributions to the Lamb shift in light muonic atoms
Evgeny Yu. Korzinin, Valery A. Shelyuto, Vladimir G. Ivanov, Robert, Szafron, Savely G. Karshenboim

TL;DR
This paper calculates one-loop light-by-light-scattering effects on the Lamb shift in light muonic atoms with atomic number up to 10, providing new effective potentials and detailed contributions of various quantum effects.
Contribution
It introduces a nonrelativistic calculation of light-by-light-scattering contributions and constructs an effective potential for virtual Delbrück scattering in muonic atoms.
Findings
Quantifies light-by-light-scattering contributions to the Lamb shift for Z ≤ 10.
Develops an effective potential for virtual Delbrück scattering.
Provides results in a nonrelativistic approximation.
Abstract
We consider one-loop light-by-light-scattering contributions to the Lamb shift of the states in light muonic hydrogen like atoms at . The contributions are of the order (with diverse dependence on the nuclear charge ). Those include the contributions of the so-called Wichmann-Kroll potential (), the virtual Delbr\"uck scattering (), etc. The results are obtained in a nonrelativistic approximation. For the calculation of the virtual-Delbr\"uck-scattering contribution, we have constructed an effective potential in the coordinate space which may be applied to other calculations in muonic atoms.
| Ion | Z | |||
|---|---|---|---|---|
| 1H | 1 | 1.356 | 0.737 | 2.950 |
| 2H | 1 | 1.428 | 0.700 | 2.800 |
| 3H | 1 | 1.454 | 0.688 | 2.751 |
| 3He | 2 | 2.908 | 0.344 | 1.375 |
| 4He | 2 | 2.935 | 0.341 | 1.363 |
| 6Li | 3 | 4.443 | 0.225 | 0.900 |
| 7Li | 3 | 4.455 | 0.224 | 0.898 |
| 9Be | 4 | 5.960 | 0.1678 | 0.671 |
| 10B | 5 | 7.460 | 0.1341 | 0.536 |
| 11B | 5 | 7.467 | 0.1339 | 0.536 |
| 12C | 6 | 8.968 | 0.1115 | 0.446 |
| 13C | 6 | 8.975 | 0.1114 | 0.446 |
| 14N | 7 | 10.48 | 0.0954 | 0.382 |
| 15N | 7 | 10.48 | 0.0954 | 0.382 |
| 16O | 8 | 11.99 | 0.0834 | 0.334 |
| 17O | 8 | 11.99 | 0.0834 | 0.334 |
| 18O | 8 | 12.00 | 0.0834 | 0.333 |
| 19F | 9 | 13.50 | 0.0741 | 0.296 |
| 20Ne | 10 | 15.00 | 0.0667 | 0.267 |
| 21Ne | 10 | 15.01 | 0.0666 | 0.267 |
| 22Ne | 10 | 15.01 | 0.0666 | 0.266 |
| Atom, state | contribution [meV] | ||
|---|---|---|---|
| Eq. (9) | direct | ||
| H () | 2.95 | ||
| H () | |||
| D () | 2.80 | ||
| D () | |||
| He+ () | 1.36 | ||
| He+ () | |||
| Ion | Z | |||||
|---|---|---|---|---|---|---|
| [] | [] | [] | [] | [meV] | ||
| 1H | 1 | 0.005 804 | 0.005 804 | 0.003 513 | 0.006 903 | |
| 2H | 1 | 0.006 073 | 0.006 073 | 0.003 736 | 0.007 734 | |
| 3H | 1 | 0.006 167 | 0.006 167 | 0.003 814 | 0.008 038 | |
| 3He | 2 | 0.040 28 | 0.010 07 | 0.024 13 | 0.2034 | |
| 4He | 2 | 0.040 49 | 0.010 12 | 0.024 26 | 0.2063 | |
| 6Li | 3 | 0.1118 | 0.012 43 | 0.076 30 | 1.474 | |
| 7Li | 3 | 0.1120 | 0.012 44 | 0.076 39 | 1.479 | |
| 9Be | 4 | 0.2227 | 0.013 92 | 0.1651 | 5.704 | |
| 10B | 5 | 0.3737 | 0.014 95 | 0.2926 | 15.81 | |
| 11B | 5 | 0.3738 | 0.014 95 | 0.2927 | 15.83 | |
| 12C | 6 | 0.5656 | 0.015 71 | 0.4600 | 35.87 | |
| 13C | 6 | 0.5657 | 0.015 72 | 0.4601 | 35.90 | |
| 14N | 7 | 0.7988 | 0.016 30 | 0.6681 | 71.00 | |
| 15N | 7 | 0.7989 | 0.016 30 | 0.6682 | 71.04 | |
| 16O | 8 | 1.073 | 0.016 77 | 0.9170 | 127.4 | |
| 17O | 8 | 1.073 | 0.016 77 | 0.9171 | 127.5 | |
| 18O | 8 | 1.074 | 0.016 77 | 0.9172 | 127.5 | |
| 19F | 9 | 1.390 | 0.017 15 | 1.207 | 212.5 | |
| 20Ne | 10 | 1.747 | 0.017 47 | 1.539 | 334.5 | |
| 21Ne | 10 | 1.747 | 0.017 47 | 1.539 | 334.6 | |
| 22Ne | 10 | 1.747 | 0.017 47 | 1.539 | 334.7 |
| Ion | Z | |||||
|---|---|---|---|---|---|---|
| [] | [] | [] | [] | [meV] | ||
| 1H | 1 | 0.000 6323 | 0.000 6323 | 0.000 3532 | 0.000 6941 | |
| 2H | 1 | 0.000 6592 | 0.000 6592 | 0.000 3687 | 0.000 7631 | |
| 3H | 1 | 0.000 6686 | 0.000 6686 | 0.000 3740 | 0.000 7880 | |
| 3He | 2 | 0.004 404 | 0.001 101 | 0.002 317 | 0.019 53 | |
| 4He | 2 | 0.004 431 | 0.001 108 | 0.002 332 | 0.019 83 | |
| 6Li | 3 | 0.013 19 | 0.001 465 | 0.008 416 | 0.1625 | |
| 7Li | 3 | 0.013 21 | 0.001 468 | 0.008 432 | 0.1633 | |
| 9Be | 4 | 0.028 39 | 0.001 774 | 0.020 34 | 0.7027 | |
| 10B | 5 | 0.050 96 | 0.002 039 | 0.039 17 | 2.117 | |
| 11B | 5 | 0.050 99 | 0.002 040 | 0.039 19 | 2.121 | |
| 12C | 6 | 0.081 68 | 0.002 269 | 0.065 75 | 5.127 | |
| 13C | 6 | 0.081 72 | 0.002 270 | 0.065 78 | 5.132 | |
| 14N | 7 | 0.1210 | 0.002 470 | 0.1006 | 10.69 | |
| 15N | 7 | 0.1210 | 0.002 470 | 0.1006 | 10.70 | |
| 16O | 8 | 0.1693 | 0.002 645 | 0.1442 | 20.03 | |
| 17O | 8 | 0.1693 | 0.002 646 | 0.1442 | 20.04 | |
| 18O | 8 | 0.1694 | 0.002 646 | 0.1442 | 20.06 | |
| 19F | 9 | 0.2269 | 0.002 801 | 0.1968 | 34.64 | |
| 20Ne | 10 | 0.2938 | 0.002 938 | 0.2585 | 56.20 | |
| 21Ne | 10 | 0.2938 | 0.002 937 | 0.2586 | 56.23 | |
| 22Ne | 10 | 0.2938 | 0.002 938 | 0.2586 | 56.24 |
| Ion | Z | |||||
|---|---|---|---|---|---|---|
| [] | [] | [] | [] | [meV] | ||
| 1H | 1 | 0.000 1116 | 0.000 1155 | |||
| 2H | 1 | 0.000 1300 | 0.000 1300 | |||
| 3H | 1 | 0.000 1353 | 0.000 1353 | |||
| 3He | 2 | 0.002 065 | 0.000 5161 | 0.000 7332 | 0.006 180 | |
| 4He | 2 | 0.002 095 | 0.000 5237 | 0.000 7518 | 0.006 394 | |
| 6Li | 3 | 0.008 568 | 0.000 9520 | 0.005 182 | 0.1001 | |
| 7Li | 3 | 0.008 597 | 0.000 9552 | 0.005 203 | 0.1007 | |
| 9Be | 4 | 0.021 43 | 0.001 339 | 0.015 22 | 0.5258 | |
| 10B | 5 | 0.041 72 | 0.001 669 | 0.032 09 | 1.734 | |
| 11B | 5 | 0.041 76 | 0.001 670 | 0.032 12 | 1.738 | |
| 12C | 6 | 0.070 29 | 0.001 952 | 0.056 73 | 4.423 | |
| 13C | 6 | 0.070 33 | 0.001 954 | 0.056 76 | 4.429 | |
| 14N | 7 | 0.1076 | 0.002 196 | 0.089 72 | 9.535 | |
| 15N | 7 | 0.1076 | 0.002 197 | 0.089 75 | 9.543 | |
| 16O | 8 | 0.1540 | 0.002 406 | 0.1315 | 18.27 | |
| 17O | 8 | 0.1540 | 0.002 407 | 0.1315 | 18.28 | |
| 18O | 8 | 0.1541 | 0.002 408 | 0.1315 | 18.29 | |
| 19F | 9 | 0.2098 | 0.002 590 | 0.1824 | 32.10 | |
| 20Ne | 10 | 0.2751 | 0.002 751 | 0.2425 | 52.72 | |
| 21Ne | 10 | 0.2751 | 0.002 751 | 0.2425 | 52.74 | |
| 22Ne | 10 | 0.2751 | 0.002 751 | 0.2426 | 52.76 |
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Light-by-light-scattering contributions to the Lamb shift in light muonic atoms
Evgeny Yu. Korzinin
Valery A. Shelyuto
D. I. Mendeleev Institute for Metrology, St.Petersburg, 190005, Russia
Pulkovo Observatory, St.Petersburg, 196140, Russia
Vladimir G. Ivanov
Pulkovo Observatory, St.Petersburg, 196140, Russia
Robert Szafron
Technische Universität München, Fakultät für Physik, 85748 Garching, Germany
Savely G. Karshenboim
Ludwig-Maximilians-Universität, Fakultät für Physik, 80799 München, Germany
Max-Planck-Institut für Quantenoptik, Garching, 85748, Germany
Pulkovo Observatory, St.Petersburg, 196140, Russia
Abstract
We consider one-loop light-by-light-scattering contributions to the Lamb shift of the states in light muonic hydrogen like atoms at . The contributions are of the order (with diverse dependence on the nuclear charge ). Those include the contributions of the so-called Wichmann-Kroll potential (), the virtual Delbrück scattering (), etc. The results are obtained in a nonrelativistic approximation. For the calculation of the virtual-Delbrück-scattering contribution, we have constructed an effective potential in the coordinate space which may be applied to other calculations in muonic atoms.
††preprint: TUM-HEP-1174/18
I Introduction
Muonic atoms give an opportunity to develop and test a bound-state QED theory and probe a nuclear structure with a specific range of parameters not available with ordinary [electronic] atoms. Recently the accuracy of the measurement of the Lamb shift in some light hydrogen like muonic atoms has been dramatically improved science:h ; science:d . The QED theory of the energy levels in muonic atoms is somewhat different from that in ordinary atoms. The Bohr radius in muonic atoms is comparable with the Compton wave length of an electron. Because of that, an important role is played by the diagrams with the closed electron loops. Those contributions are specific for muonic atoms. The most important are those due to vacuum polarization. Their contribution to the energy is of the order .
Effects of the virtual light-by-light scattering contribute to higher orders. There are three types of such contributions, characteristic diagrams which are presented in Fig. 1. They are all of the order , but their dependence on the value of the nuclear charge is different.
The contribution (see the graph 1:3 in Fig. 1) is the so-called Wichmann-Kroll (WK) contribution, which has been studied for a while (see, e.g., bor_rin ; VASH-book ). A number of the results have been achieved for muonic atoms using certain numerical approximations of the exact WK potential. In particular, the approximations, introduced in huang and bor_rin on the basis of the results of numerical integration in vogel , were numerously applied (e.g., in pach ; bor_rin ; EGS ). The result for the Lamb shift with the accuracy sufficient for applications in H was found in EGS and confirmed in bor_h ; LbL1 ; LbL2 . In LbL1 ; LbL2 the result was also confirmed by direct calculations. The WK contributions to the Lamb shift for some other light muonic atoms are obtained in, e.g., bor_d ; bor_he ; VP2rel .
The term is due to the virtual Delbrück scattering (see the 2:2 diagram in Fig. 1). It has also been studied for quite a long period (see, e.g., bor_rin ; VASH-book ). Still, some questions have been resolved only recently LbL1 .
The initial calculations were based on a so-called scattering approximation scattering (where the Coulomb muon propagator is substituted for a free one). The substitution by itself is incorrect (see, e.g., discussion in VASH-book ; LbL1 ); however, the formulas which were eventually used in the numerical calculations were nevertheless correct (see below). Results on the contribution to the Lamb shift in some light atoms were published, e.g., in bor_rin ; bor_h , but they were not very accurate.
The third type of contributions (see the 3:1 plot in Fig. 1) have not been calculated until recently. It was studied in LbL1 ; LbL2 , where also the virtual-Delbrück-scattering contribution was found with a sufficient accuracy for several light muonic atoms.
A kind of theorem on the 2:2 and 3:1 contributions was announced in LbL2 and proven in LbL1 . The papers considered an approximation of a static muon, where its nonrelativistic propagator is presented with a function over the energy. It was proven that the approximation is a valid one. We discuss the accuracy of the approximation in this paper (see Sec. II). Using that approximation LbL2 ; LbL1 , the results on the 2:2 and 3:1 contributions to the Lamb shift in muonic hydrogen, deuterium and helium ions have been found (see VP2rel for T). It was also demonstrated that the related limit can be achieved both from the diagrams with the bound-muon Green’s function (as shown in Fig. 1) and from those with the free Green’s function (as were used in the scattering approximation in bor_rin ; bor_h ). As far as the static-muon approximation is applicable, one may use both types of diagrams with the same result, which validates the working formulas used in bor_rin ; bor_h .
In this paper we consider the effective potential for the virtual-Delbrück-scattering contribution to the Lamb shift in light muonic two-body atoms. We use the representation of the potential in momentum space in terms of an integral over Feynman parameters LbL1 and study the effective potential in the coordinate space by means of an analytic Fourier transform and subsequent numerical integrations over the Feynman parameters. For the effective potential in the coordinate space, we find both asymptotics (at and ). (Here and throughout the paper we apply the relativistic units in which .) Eventually, we fit the numerical results and asymptotics, obtained here. The approximation is accurate at the level of in the area where the muon wave function of low states is localized.
Our main results are related to the virtual-Delbrück-scattering contribution to the Lamb shift; however, we present numerical results for all three light-by-light (LbL) contributions (see Fig. 1), because their comparison can be useful.
The Lamb-shift interval cannot be successfully measured in all the two-body muonic atoms (because of the range of the interval); however, the theory of the Lyman- transition is very similar. The data on such gross-structure transitions play an important role in determination of the rms charge radius of a large variety of elements (see, e.g., radii ). In this paper we tabulate the virtual light-by-light-scattering contribution to the Lamb shift of the states which is sufficient for the calculation of both the interval and the energy of the transition. The considered range of the nuclear charge is .
II The effective potential and the static-muon approximation
As demonstrated in LbL1 , once we can neglect various contributions to the muon propagator, such as the binding energy and those related to momentum transfer [between the muon and the electron loop] in comparison with its energy transfer , we arrive at the nonrelativistic propagator reduced to . For ( is the principle quantum number), the energy transfer is determined by the scale. In the opposite case, when , the characteristic value of is determined by the value of the momentum (in the LbL loop), which in its turn is determined by the characteristic atomic momentum . That means that once , we can apply the static-muon approximation. (In LbL1 we considered a stronger condition .) All that is related, indeed, to only 2:2 and 3:1 contributions. The standard WK contribution does not require any conditions on the muon but only on the static regime of the nucleus. Those conditions are weaker and the validity of the WK potential is due to relativistic-recoil effects, i.e., due to corrections which are of higher order in both small parameters of the two-body Coulomb problem, and , where is the nuclear mass.
Once the static-muon approximation is applicable, we arrive at a ”double-external-field” limit, the diagrams for which are presented in Fig. 2. In particular, that allows us to immediately set a relation between the 3:1 contribution and the 1:3 one (WK);
[TABLE]
since the related integrands differ by their normalization only. Note that Eq. (1) is correct only under the static-muon approximation. The corrections beyond the approximation are of different orders for and .
The potential for the 1:3 contribution was studied for a while and there are a number of efficient approximations, such as those mentioned above from huang and bor_rin . (Still, we revisit the problem in Sec. IV.)
An effective potential for the 2:2 contribution, an evaluation of which is the main purpose of this paper, is considered in detail in the next section.
III The effective potential for the virtual-Delbrück-scattering
contribution
Following LbL1 , the contribution of virtual Delbrück scattering to the Lamb shift in light muonic atoms can be presented in terms of a certain potential. In the momentum space the result reads LbL1
[TABLE]
where the potential is discussed in details in LbL2 and
[TABLE]
is the form factor of the atomic state, while is its nonrelativistic Coulomb wave function (with the reduced mass ).
The potential is presented in momentum space as an integral over the Feynman parameters LbL1
[TABLE]
where , , , and are bulky dimensionless functions of those parameters considered in LbL1 . The parameter is to distinguish two diagrams contributing to : stands for the left 2:2 graph (see Fig. 2) and is for the right one.
The dependence on is simple, which allows us to immediately perform the Fourier transformation
[TABLE]
and to obtain a result in the coordinate space, which reads
[TABLE]
The explicit representation of the potential is cumbersome and for practical applications we further look for an efficient approximate formula. To derive it we first find the value of the potential in certain points in the coordinate space (see Fig. 3) and then fit them with a Padé approximation.
To improve the accuracy of the fit, prior to fitting, we look for the asymptotics. The potential behaves as at short distances, as one should expect from (6), while at long distances it is . The general situation is illustrated in the plot in Fig. 3. The range of characteristic values of , which are of interest for light muonic atoms, is summarized in Table 1.
The short-distance asymptotic coefficient can be directly established from (6) in a rather straightforward way. The result of the numerical integration reads
[TABLE]
The large-distance asymptotic behavior is not that simple to establish from (6). Considering the LbL contributions (see Fig. 1) in the channel, we note that some pure photonic intermediate states are possible there, which sets the branch point for to zero and eventually leads to a certain behavior at large distances for each of the LbL potentials (cf. WK1 ). In the case of in thedd form of (6), that technically means a singularity of the effective dispersion-relation variable (cf. (4)) at , which should transform the exponential factor in (6) to .
Fortunately, the asymptotic behavior of the 2:2 potential can be successfully studied in a different way; namely, we find it from the virtual-Delbrück-scattering amplitude for soft photons rev:vD1 ; rev:vD2 ; vDs (cf. LbL:CS ) as
[TABLE]
With the asymptotic coefficients in hand, we fit the numerical results. The fit reads
[TABLE]
where . The fit has for 22 degrees of freedom. We estimate the accuracy of the fit as for . In the interval of the uncertainty gradually increases to a few percent level. For higher , thanks to the correct asymptotic behavior, the error does not exceed that level.
As an independent test of our fit, we compare the results obtained by using the fit for the Lamb shift in the lightest two-body muonic atoms with the direct ones LbL1 ; LbL2 (see Table 2). The results are in perfect agreement within our estimation of the uncertainty of the fit as .
The virtual-Delbrück-scattering situation is very different from the WK one. As mentioned, the WK potential WK1 is valid when one can neglect the recoil effects, i.e., it is a result of an expansion not only in , but also in . Because of the recoil nature of the corrections, the WK potential is applicable in both ordinary and muonic atoms. In the former we are interested in a large range of distances at , while the latter deals only with or . The 2:2 potential is applicable only for muonic atoms LbL1 ; LbL2 and therefore the area with and even with is of low interest. It still may appear in evaluation of the energy for the highly excited states with , but most of the applications rely on a study of the lower states with . For such states the accuracy of the Padé approximation (9) is at the level of . Note, that this is the accuracy of the approximation of potential. Meanwhile, the very applicability of that potential due to the static muon approximation has lower accuracy (see above).
As an example of applicability of the area to practical cases, we mention neutral antiprotonic helium, where the characteristic size of the antiproton orbit is comparable with the orbit of an electron in a hydrogen atom (see, e.g., antih ).
IV Numerical results
The purpose of the paper is a derivation of an effective potential for the 2:2 contribution to the muonic-atom Lamb shift at medium , which has been done in the previous section. It is interesting to compare the numerical results with those from other LbL terms, and in particular, with the WK ones.
There are two fits for the WK potential for the muonic atoms, which are available in literature. (The potential is valid by itself for ordinary and muonic atoms; however, the purpose of the fit determines the range of the distances of interest (see above).) One of them is huang
[TABLE]
Another fit applied in numerical calculations in muonic atoms is bor_rin
[TABLE]
Both fits are based on numerical calculations by Vogel vogel for the interval of and in that area the fits well agree with the numerical results (at the level of ). They both utilize the known leading asymptotic term at low . They are different in area . The advantage of (10) is more smooth behavior around and therefore a better extrapolation to the low end of the interval, while the fit in (11) accommodates the asymptotic term at and is better at high end of the interval.
We use our own fit of Vogel’s data vogel
[TABLE]
which fits the data for with a fractional uncertainty better than and correctly reproduces the asymptotics at low WK1 (see also blomqvist ; bell ) and at high WK1 (see also huang ; manakov ). In contrast to the fit (11) from bor_rin , our fit in (12) has smooth behavior at 6taround .
The application of the fits to the Lamb shift in muonic hydrogen is rather questionable (see Table 1), since we essentially need to integrate over an interval outside of the data area of vogel , which was used to derive the fit. The smooth behavior at around and a correct asymptotics (mentioned above) should deliver a reasonable result, but its accuracy is unclear.
Previously, while calculating the results for muonic hydrogen, deuterium, and helium LbL1 ; LbL2 ; VP2rel we have used a direct calculation instead of the fits. To verify the accuracy of the previous fits and our fit, we compare our results of a direct calculation and the results from the fits for for a few light atoms where the characteristic values of are the largest (see Table 3). The error of our fit is about 1%, while for the others it is at a few-percent level. Eventually we estimate the accuracy of our fit as follows; at it is below , and it gradually reduces for and down to a 1% level.
The results for states in a two-body muonic atom are summarized in Tables 4, 5, and 6 for all three LbL contributions (the 1:3, 2:2, 3:1 ones). The uncertainty of the fits is discussed above, as well as the uncertainty of the static-muon approximation.
V Conclusions
In conclusion, we have derived a representation for an effective potential induced by the virtual Delbrück scattering in the leading nonrelativistic approximation. We have obtained its numerical values in a number of points in the coordinate space and found an efficient Padé approximation. The accuracy of the Padé approximation is the highest for , which allowed us to find the contributions to the Lamb shift of the low states in light two-body muonic atoms. We estimate the accuracy of the numerical evaluation as at the level of one part in a thousand, which is higher than the accuracy of the leading nonrelativistic approximation by itself.
The uncertainty of the Padé approximation for the potential is the best for (at the level of ), and it gradually increases to the few-percent level for . The data of the numerical evaluation of the potential itself at higher are not accurate enough; however, the Padé approximation is constrained by the long-distance asymptotic behavior, which we have established by an independent evaluation.
In particular, we have tabulated the related contributions to the Lamb shift of the states in muonic atoms with . Those states are sufficient for two important problems, namely, for a theory of the Lamb shift and of the Lyman- interval.
We have also compared the results for the virtual-Delbrück-scattering contribution and the Wichmann-Kroll one. At they are comparable (being of opposite signs). They increase with the value of , but the Wichmann-Kroll one increases faster. At the virtual-Delbrück-scattering contribution is between 10 and 20% of the Wichmann-Kroll contribution depending on the state.
Acknowledgments
The work was supported in part by RSF (under grant # 17-12-01036). The work on calculation of the long-distance behavior was also supported by DFG (Grant No. KA 4645/1-1). The authors are grateful to Andrzej Czarnecki, Aleksander Milstein, Akira Ozawa, Krzysztof Pachucki, and Thomas Udem for useful and stimulating discussions.
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