In Situ Ion Induced Gelation of Colloidal Dispersion of Laponite: Relating Microscopic Interactions to Macroscopic Behavior

TL;DR

This study investigates how exposure to carbon dioxide induces ion formation in Laponite dispersions, leading to gelation, and relates microscopic ionic interactions to macroscopic rheological behavior using DLVO theory.

Contribution

It demonstrates the in situ ion-induced gelation process in Laponite dispersions under CO2 and links microscopic interactions to macroscopic rheological changes through DLVO analysis.

Findings

CO2 exposure induces magnesium and lithium ions in Laponite dispersion.

Enhanced elastic and viscous moduli observed under CO2 compared to air.

DLVO analysis qualitatively explains the evolution of rheological properties.

Abstract

Aqueous dispersion of Laponite, when exposed to carbon dioxide environment leads to in situ inducement of magnesium and lithium ions, which is, however absent when dispersion is exposed to air. Consequently, in the rheological experiments, Laponite dispersion preserved under carbon dioxide shows more spectacular enhancement in the elastic and viscous moduli as a function of time compared to that exposed to air. By measuring concentration of all the ions present in a dispersion as well as change in pH, the evolving inter-particle interactions among the Laponite particles is estimated. DLVO analysis of a limiting case is performed, wherein two particles approach each other in a parallel fashion a situation with maximum repulsive interactions. Interestingly it is observed that DLVO analysis explains the qualitative details of an evolution of elastic and viscous moduli remarkably well thereby successfully relating the macroscopic phenomena to the microscopic interactions.