Bound states of a pair of particles on the half-line with a general interaction potential
Sebastian Egger, and Joachim Kerner, and Konstantin Pankrashkin

TL;DR
This paper investigates the spectral properties of a two-particle quantum system on the half-line with general interactions, establishing the essential spectrum, the existence of bound states below it, and finiteness of discrete eigenvalues.
Contribution
It characterizes the essential spectrum and proves the existence and finiteness of bound states for a broad class of two-particle potentials on the half-line.
Findings
Essential spectrum characterized
Existence of eigenvalues below the essential spectrum proven
Discrete spectrum contains finitely many eigenvalues
Abstract
In this paper we study an interacting two-particle system on the positive half-line. We focus on spectral properties of the Hamiltonian for a large class of two-particle potentials. We characterize the essential spectrum and prove, as a main result, the existence of eigenvalues below the bottom of it. We also prove that the discrete spectrum contains only finitely many eigenvalues.
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Bound states of a pair of particles
on the half-line with a general interaction potential
Sebastian Egger
Department of Mathematics, Technion-Israel Institute of Technology, 629 Amado Building, Haifa 32000, Israel
,
Joachim Kerner
Department of Mathematics and Computer Science, FernUniversität in Hagen, 58084 Hagen, Germany
and
Konstantin Pankrashkin
Laboratoire de Mathématiques d’Orsay, Univ. Paris-Sud, CNRS, Université Paris-Saclay, 91405 Orsay, France
Abstract.
In this paper we study an interacting two-particle system on the positive half-line . We focus on spectral properties of the Hamiltonian for a large class of two-particle potentials. We characterize the essential spectrum and prove, as a main result, the existence of eigenvalues below the bottom of it. We also prove that the discrete spectrum contains only finitely many eigenvalues.
1. Introduction
In this paper we are concerned with spectral properties of an interacting two-particle system moving on the half-line . More specifically, we consider the (two-particle) Hamiltonian in given by
[TABLE]
with an interaction potential belonging to a large class covering all physically meaningful potentials including, e.g., quadratic and Lennard-Jones-type potentials. Note that the factor in the argument of is only chosen for further convenience. Very informally, our main result is that if the potential creates a bound state for the respective one-dimensional Schrödinger operator on the half-line, then it creates at least one eigenvalue of with a strictly lower energy.
The present work is a far-reaching extension of the previous work [KM] in which a similar result was obtained for a specific class of hard wall potentials . As described in [K17, K18], the presence of a discrete spectrum leads to a (Bose-Einstein) condensation of pairs in a gas of bosonic, non-interacting pairs with each pair described by (1). A condensation of pairs of electrons, on the other hand, is the key mechanism in the formation of the superconducting phase in type-I superconductors [C, BCS]. Hence, the extension of the model discussed in this paper is expected to have also interesting applications in solid-state physics. One should emphasize on the fact that only very few two-particle problems admit an explicit solution, see e.g. [BERW], so qualitative results are of a particular importance.
Let us introduce some notions used throughout the paper: To keep the notation as simple as possible, we will work with real-valued Hilbert spaces. For a self-adjoint and semi-bounded operator we denote by its domain and by the domain of the associated bilinear form (which will often referred to as the form domain of ). The bilinear form itself will be denoted as , the spectrum and the essential spectrum of will be denoted by and respectively.
Let be a real-valued potential on with the following properties:
- (A)
and , 2. (B)
The one-particle Schrödinger operator
[TABLE]
in , which is rigorously defined through its form
[TABLE]
is such that the bottom of the spectrum is an isolated eigenvalue, 3. (C)
The bottom eigenvalue is strictly lower than the values of at infinity, i.e. it holds .
The assumption (C) is to avoid potentials with a pathological behavior, and it holds for the physically reasonable cases. It is well known that that the assumptions (B) and (C) are satisfied in two important cases:
- (a)
for ,
- (b)
and with \displaystyle\int_{{\mathbb{R}}_{+}}\big{(}v(x)-v_{\infty}\big{)}\mathrm{d}x<0
(see Propositions A.9 and A.10 in Appendix).
For potentials which are sufficiently regular near [math], for example, for , it is standard to see that the above operator corresponds to the Neumann condition at the origin. In general, the operator can be in the limit point case at [math] (if diverges very fast at zero) in which case the characterization of boundary conditions is more involved. However, this subtlety is of no importance for our constructions in the following.
The associated two-particle Schrödinger operator
[TABLE]
in is rigorously defined through its form,
[TABLE]
note the factor in the argument of which is chosen for convenience in order to have less factors in later computations. Our results are summarized as follows:
Theorem 1.1**.**
The essential spectrum of is , and its discrete spectrum is non-empty and finite.
We remark that the presence of a non-empty discrete spectrum is probably the most important result. It relies on a rather involved construction of a test function whose structure was proposed in [LP] for a different problem involving specific potentials with explicitly known ground states, and it also appeared in e.g. [HM, P]. So we propose another extension to rather general operators and hope that it can be used beyond our framework (See e.g. Remark 2.2 below.) The proof of the finiteness of the discrete spectrum essentially follows the scheme of [MT] for another specific operator and essentially represents a realization of the Feshbach projection method, which was also used in [KP]. A new ingredient is delivered by the fact that some new properties of the ground state of should be established first. The fact that we work with rather singular potentials , which can be non-integrable near [math], brings a number of technical subtleties concerning the regularity of functions, and we collect the respective results on one-dimensional Schrödinger operators in Section A.
2. Proof of Theorem 1.1
2.1. Reductions by symmetries
Let us first perform some standard reductions in order to deal with a model case. Denote
[TABLE]
and consider the diffeomorphism (rotation by )
[TABLE]
and the unitary transform (pull back) , . Using the standard change of variables one easily checks that
[TABLE]
with being the operator in given by its form
[TABLE]
which is then unitarily equivalent to . To use the parity with respect to we consider the right half of ,
[TABLE]
and the unitary transform
[TABLE]
If one introduces self-adjoint operators in given by
[TABLE]
then one easily checks that
[TABLE]
It follows that (hence, also ) is unitarily equivalent to . As the bilinear form of is an extension of that for , it follows by the min-max principle that and that the number of eigenvalues of below does not exceed that for .
Therefore, \inf\sigma_{\text{ess}}(H)=\min\big{\{}\inf\sigma_{\text{ess}}(Q_{-}),\inf\sigma_{\text{ess}}(Q_{+})\big{\}}=\inf\sigma_{\text{ess}}(Q_{+}), and the non-emptyness and finiteness of the discrete spectrum of will imply the non-emptyness and finiteness of the discrete spectrum of . This shows that Theorem 1.1 becomes a consequence of the following assertion, whose proof will be given in the rest of the section:
Proposition 2.1**.**
The essential spectrum of the operator is , and its discrete spectrum is non-empty and finite.
Remark 2.2**.**
It is clear that the above operators correspond to the restrictions of the initial operator to the symmetric/anti-symmetric functions, i.e. . While the operator is “dominated” by the operator (in the sense that the qualitative spectral picture for is determined by that of only), it can be studied on its own, and the analog of Proposition 2.1 has then the following form:
Proposition 2.3**.**
Let be the operator in with
[TABLE]
If the bottom of the spectrum is an isolated eigenvalue with , then the essential spectrum of is and the discrete spectrum is non-empty and finite.
This can be proved by a literal repetition of the proof of Proposition 2.1 given in the following three subsections (see also Remark A.11 in Appendix concerning ).
2.2. Essential spectrum
Let us show the equality by establishing separately the inclusions in both directions. The constructions of this section are very standard and are given to render a self-contained presentation.
In a first step, let us prove first that employing an operator bracketing argument: For that, we partition into three subdomains , , using the straight lines and with large enough. More precisely,
[TABLE]
Define self-adjoint operators in , , through their bilinear forms
[TABLE]
Using the canonical orthogonal projections , defined just as restrictions to , we observe that and that and, in addition, that the map
[TABLE]
is unitary. It follows by the min-max principle that
[TABLE]
Since is a bounded Lipschitz domain, the form domain is compactly embedded in , which implies that the spectrum of is purely discrete. Furthermore, we have for all with chosen sufficiently large, due to to the assumption (C) on the potential . It follows that
[TABLE]
To analyze we remark first that it admits a separation of variables,
[TABLE]
where is the operator in associated with the form
[TABLE]
while acts in , being defined via its associated form
[TABLE]
i.e. acts as with the Neumann boundary condition at , and . By (4) there holds . It is standard to see (see Proposition A.5) that . By (3) one has \inf\sigma_{\text{ess}}(Q_{+})\geq\liminf_{L\to+\infty}\min\big{\{}\varepsilon_{0},\inf\sigma(q^{N}_{L})\big{\}}=\varepsilon_{0}.
Now let us show the reverse inclusion by constructing a suitable Weyl sequence. For that, let be a smooth function with such that for and for . Pick any . For define with
[TABLE]
Then vanishes outside the rectangle , and . For large one estimates, with a suitable ,
[TABLE]
On the other hand, with
[TABLE]
where with some one has
[TABLE]
One has \big{(}Q_{+}-(\varepsilon_{0}+k^{2})\big{)}\varphi(x_{1},x_{2})=\Phi_{n}(x_{1})g_{n}(x_{2})+f_{n}(x_{1})\Psi_{n}(x_{2}) and
[TABLE]
Therefore,
[TABLE]
due to . Hence, for any , in other words, . As the set has no isolated points, it follows that .
2.3. Existence of discrete eigenvalues
In this section we show that the discrete spectrum of is non-empty.
Recall that the bilinear form of is given by
[TABLE]
As , it follows by the min-max principle that the non-emptyness of the discrete spectrum follows from the existence of a function satisfying the strict inequality .
We will seek for such a function in the form , with being as previously the ground state of and a function to be specified. Due to the standard regularity considerations (see Appendix) there holds . With some we introduce
[TABLE]
It is easily checked (see Proposition A.4) that for any provided , which is assumed from now on. Finally we introduce a smooth cut-off function and the associated truncations , , by
[TABLE]
The function defined by belongs then to for any . A calculation then yields the following:
[TABLE]
An integration by parts ( which is still possible for singular potentials , see Proposition A.2 in the appendix) gives
[TABLE]
and which allows us to write
[TABLE]
Integrating the middle term on the right-hand side by parts one obtains
[TABLE]
One has and , which shows that the first summand on the right-hand side vanishes, and
[TABLE]
Taking into account one rewrites (6) as
[TABLE]
In order to show that the term can be made strictly negative one uses first the expressions for and to compute
[TABLE]
and
[TABLE]
which yields, for ,
[TABLE]
One then decompse the above term as follows:
[TABLE]
We recall that and , which ensures the finiteness of the integrals. One easily sees that , while . We then estimate
[TABLE]
and using (7) one has . Hence choosing any value \rho\in\big{(}\frac{1}{2},1\big{)} we have for large , which concludes the proof.
2.4. Finiteness of the discrete spectrum
In this section we prove that has only finitely many eigenvalues in .
We first introduce a pair of smooth functions such that for , for , and . We set, for and ,
[TABLE]
Then, for any we have and, by direct computation
[TABLE]
Consider two following (overlapping) subdomains of :
[TABLE]
and define self-adjoint operators in , , by their forms
[TABLE]
Let us return back to (8). The functions vanish outside , , and their restrictions to belong to . In addition, one has pointwise. This allows one to rewrite (8) as
[TABLE]
Consider an auxiliary operator defined on , then , with
[TABLE]
The linear map
[TABLE]
is isometric and, hence, injective, with , and Eq. (9) reads then as . Hence, if one denotes be the th eigenvalue of a self-adjoint operator , then the min-max principle gives, for any ,
[TABLE]
where and stand for -dimensional subspaces. Hence, if for a self-adjoint operator and we denote by the number of eigenvalues of in , then it follows from the above constructions that
[TABLE]
Hence, it is sufficient to show that are finite for .
Let us start with : Consider the decomposition of created by the line , i.e.
[TABLE]
and consider the operators in with , given by their forms
[TABLE]
The bilinear form for is an extension of the bilinear form for , and the min-max principle shows that the eigenvalues of can not be lower than the respective eigenvalues of . In terms of the counting functions this leads to
[TABLE]
The domain is bounded, Lipschitz and is compactly embedded into , which implies that is with compact resolvent, and then for any fixed . On the other hand, the upper bound with some and the assumption (C) on the potential imply that for sufficiently large one has for all . It follows that has no spectrum below and . Therefore, there exists such that for any .
In order to conclude it remains to show that for large ; note that depends on . Due to the fact that the functions in the form domain of vanish at the line they can be extended by zero to functions in . Therefore, if one considers the operator in given by
[TABLE]
then it follows by the min-max principle that . Therefore, it is sufficient to show that for large .
The subsequent construction is inspired by the representation
[TABLE]
where is in and is identified with the associated multplication operator.
Let be the orthogonal projection on in , then is the orthogonal projection on in , i.e.
[TABLE]
Notice that is exactly the spectral projector on for (due to the fact that is a simple eigenvalue, see Proposition A.3) and it commutes with . We set . Taking into account that both and are in , for we obtain
[TABLE]
As is bounded, using Cauchy-Schwarz and triangular inequalities we estimate
[TABLE]
Due to the assumption (B) on , the eigenvalue of is isolated, hence, E_{2}:=\inf\big{(}\sigma(h)\setminus\{\varepsilon_{0}\}\big{)}>\varepsilon_{0}, and
[TABLE]
It follows that, taking into account that the operator is non-negative,
[TABLE]
Summing up all the computations after (11) yields
[TABLE]
Let be the self-adjoint operator in given by
[TABLE]
and be the operator of multiplication by in , which is bounded and self-adjoint. Considering the unitary map
[TABLE]
we rewrite (12) as , which due to the min-max principle implies
[TABLE]
As is fixed and , for sufficiently large and some one has the lower bound showing that has no spectrum in and hence . The estimate (13) takes the form , and now it is sufficient to show that for being sufficiently large.
In order to study we rewrite, using the convention (10),
[TABLE]
Recall that for due to the spectral theorem one has , i.e. . Consequently, one has
[TABLE]
with being the self-adjoint operator in given by the form
[TABLE]
defined on . As the map is unitary, one sees that is unitarily equivalent to , which yields .
Now it is sufficient to show that has only finitely many negative eigenvalues. The task is simplified by the fact that is a standard one-dimensional Schrödinger operator. Recall that, by construction one has and
[TABLE]
i.e. vanishes except for . Due to
[TABLE]
it follows that is bounded, continuous, and for . In view of the well-known Bargman estimate (see, e.g., Theorem 5.1 in Chapter 2.5 of [BS]) in order to obtain it is sufficient to show
[TABLE]
(recall that , and then as well).
In order to obtain (15) we recall that due to the standard Agmon estimate (see e.g. Corollary A.7 in Appendix) for some one has
[TABLE]
For one then estimates, using (14),
[TABLE]
with c_{1}:=\Big{(}\|W\|_{\infty}+R\|W\|_{\infty}^{2}\Big{)}e^{2Ra}. Hence,
[TABLE]
This proves (15) and completes the proof.
Appendix A Some constructions for Schrödinger operators with singular potentials
In this section we recall briefly some facts related to Schrödinger operators with singular potentials. All these facts are well-known to the specialists but we are not aware of their presentation within a single reference and in a suitable form under our rather weak assumptions on the potential , and we decided to collect them here with proofs. An interested reader may refer e.g. to [EGNT] for a more detailed discussion of singular potentials.
For the whole of this section, we write and let be a real-valued potential with v_{-}:=\max\{-v,0\big{\}}\in L^{\infty}({\mathbb{R}}_{+}). Let be the self-adjoint operator in generated by its bilinear form
[TABLE]
Recall that stands for the form domain, while the operator domain is denoted by . In other words, a function belongs to the operator domain of and if and only if
[TABLE]
As the preceding equality holds for all , it follows that acts as . We give a proof of the following technical fact:
Proposition A.1**.**
Let and with being constant in a neighborhood of [math], then and .
Proof.
Remark first that . Then, we simply need to show that
[TABLE]
for any . On the other hand, the assumption already gives
[TABLE]
Taking the difference between (16) and (17) one sees that it is sufficient to show the equality
[TABLE]
which reads in a more detailed form as
[TABLE]
One clearly has
[TABLE]
By regrouping the terms one arrives at (18), which concludes the proof. ∎
For each one has . Due to the inclusions it follows that and then and . That implies that the values and make sense for any . Let us add some precisions on the behavior near [math] and .
Proposition A.2**.**
Let , then
[TABLE]
and the integration-by-parts formula
[TABLE]
holds for .
Proof.
In view of the above regularity of , for any one has the standard integration by parts
[TABLE]
and we need to show that the passage to the limit is possible. By the definition of one has
[TABLE]
implying
[TABLE]
Let such that near zero, then due to Proposition A.1, and (21) also holds for replaced by . As is identically zero at infinity and coincides with near the origin, one obtains
[TABLE]
Using (21) again one has . By passing to the limit in (20) one concludes the proof. ∎
Assume from now on that the bottom of the spectrum of is an eigenvalue.
Proposition A.3**.**
The eigenvalue is simple, and the corresponding eigenfunction can be chosen strictly positive.
Proof.
Let with be given. Due to the min-max principle this is equivalent to
[TABLE]
For one has h\big{[}|\psi_{0}|,|\psi_{0}|\big{]}\leq h[\psi_{0},\psi_{0}] and \big{\|}|\psi_{0}|\big{\|}_{L^{2}({\mathbb{R}}_{+})}=\|\psi_{0}\|_{L^{2}({\mathbb{R}}_{+})}, which shows that .
Assume that for some , then from it follows that . Let us show that this implies for all . That is essentially Gronwall’s lemma, but we prefer to include it for completeness. To be definite, consider (the other case is considered in the same way). The fact can be rewritten as
[TABLE]
Then for and one has
[TABLE]
for all and . Therefore, , so by integrating between and one arrives at
[TABLE]
Due to and one obtains
[TABLE]
As is arbitrary, one obtains for , which implies for .
We conclude that an eigenfunction cannot vanish, hence, up to a multiplicative factor it is strictly positive. As two strictly positive functions cannot be orthogonal in , the eigenvalue is simple. ∎
For the rest of the section, let be the strictly positive eigenfunction for , with a unit -norm.
Proposition A.4**.**
Let , then the function
[TABLE]
is in for any .
Proof.
Since , we only have to take care of the derivative. A direct calculation shows that
[TABLE]
Let be the inverse of
[TABLE]
which is a diffeomorphism due to (Proposition A.3), then
[TABLE]
and consequently
[TABLE]
As , the integral is finite for . ∎
For the rest of the section we assume finally that
[TABLE]
For , define two operators in by
[TABLE]
with form domains
[TABLE]
and denote by the respective lowest eigenvalues.
Proposition A.5**.**
There holds .
Proof.
By the min-max principle one has for all .
Let be the operator on associated with the form
[TABLE]
Again, the min-max principle then implies that
[TABLE]
On the other hand, \inf\sigma(h^{N}_{L}\oplus\widetilde{h}^{N}_{L})=\min\big{\{}\varepsilon_{0}^{N}(L),\inf\sigma(\widetilde{h}^{N}_{L})\big{\}}, and due to the assumption (22) for sufficiently large one has . It follows from (23) that for large .
Now let us take with
[TABLE]
and set , . For any we obtain
[TABLE]
for some constant . Since for we conclude that and then
[TABLE]
Using the assumption (22) on , one can choose sufficiently large to have in . Due to there holds
[TABLE]
Therefore, for large one has, uniformly in ,
[TABLE]
which implies due to the min-max principle. Summing up we obtain, for large enough,
[TABLE]
which proves the statement. ∎
In the next result we recall an Agmon-type estimate for the ground state of . Recall that was chosen strictly positive and normalized in .
Proposition A.6** (Agmon-type estimate).**
For any there is with for such that
[TABLE]
Proof.
Let us take a sufficiently large such that for ; the value of will be adjusted later. Define as above, and for define
[TABLE]
then and \big{|}\phi^{\prime}_{L}(x)\big{|}\leq\theta\mathds{1}_{x>R}(x)\sqrt{v(x)-\varepsilon_{0}}, where stands for the indicator function of the set \big{\{}x\in\mathbb{R}_{+}:x>R\big{\}}.
Let us show first that
[TABLE]
By construction, , so and
[TABLE]
Furthermore, , and the second summand is in due to , while the first summand is finite due to
[TABLE]
Hence, the claim (24) is proved.
Now we compute
[TABLE]
Due to (24) one can transform the last summand on the right-hand side as
[TABLE]
which yields
[TABLE]
Now let us pick any . The min-max principle applied to gives
[TABLE]
Hence, for large one has due to Proposition A.5, and
[TABLE]
By combining this last inequality with (25) we arrive at
[TABLE]
This rewrites as
[TABLE]
and taking into account the above choice of and we arrive at
[TABLE]
As was arbitrary, we may assume that , then for large one has in , and it follows from the preceding inequality that
[TABLE]
Consequently,
[TABLE]
or, in a detailed form,
[TABLE]
As the constant on the right-hand side is independent of the choice of , the statement then follows by taking the limit . ∎
We prefer to give a simplified version of the preceding estimate, which will be easier to use in the main text:
Corollary A.7**.**
For some there holds
[TABLE]
Proof.
Due to the assumption (22) on , for some one has for large , and then the function in Proposition A.6 satisfies the inequality for all (with a fixed ), which leads to
[TABLE]
which gives the claim with . ∎
We finish this appendix by mentioning two classical cases for which the assumption (22) is satisfied. Recall that
[TABLE]
Proposition A.8**.**
There holds .
Proof.
Let be the operator on given by its bilinear form
[TABLE]
Then the min-max principle implies for any . The operator has compact resolvent and an empty essential spectrum, hence, . For any one can choose a large to have in , which leads to . It follows that
[TABLE]
As is arbitrary, this gives the result. ∎
Proposition A.9**.**
If , then the bottom of the spectrum of is an isolated eigenvalue with .
Proof.
In this case by Proposition A.8, i.e. is with compact resolvent. Its lowest eigenvalue is then automatically isolated, and the inequality is just the finiteness of . ∎
Proposition A.10**.**
Assume that and that with
[TABLE]
then the bottom of the spectrum of is an isolated eigenvalue, and it satisfies .
Proof.
In view of Proposition A.8 it is sufficient to establish the existence of eigenvalues in , for which it is sufficient to find a function with .
For consider , then with
[TABLE]
and the right-hand side converges to a strictly negative limit as . ∎
Remark A.11**.**
It is easily seen that all assertions of this Appendix, except Proposition A.10, remain valid for if one replaces the operator by the operator defined in (2), which provides necessary technical components to prove Proposition 2.3.
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