# Chemical Aspects of the Antiferromagnetic Topological Insulator MnBi$_{2}$Te$_{4}$

## TL;DR

This study reports the synthesis, structural characterization, magnetic properties, and topological surface states of MnBi₂Te₄, confirming its status as a 3D antiferromagnetic topological insulator with potential for studying magnetic-topological crossover.

## Contribution

It demonstrates scalable synthesis of high-quality MnBi₂Te₄ crystals and provides comprehensive experimental evidence of its magnetic and topological properties, advancing its use as a platform for related studies.

## Key findings

- Confirmed antiferromagnetic ordering below 24 K
- Observed gapped Dirac cone surface state
- Identified antisite defects and Mn vacancies

## Abstract

Crystal growth of MnBi$_{2}$Te$_{4}$ has delivered the first experimental corroboration of the 3D antiferromagnetic topological insulator state. Our present results confirm that the synthesis of MnBi$_{2}$Te$_{4}$ can be scaled-up and strengthen it as a promising experimental platform for studies of a crossover between magnetic ordering and non-trivial topology. High-quality single crystals of MnBi$_{2}$Te$_{4}$ are grown by slow cooling within a narrow range between the melting points of Bi$_{2}$Te$_{3}$ (586 {\deg}C) and MnBi$_{2}$Te$_{4}$ (600 {\deg}C). Single crystal X-ray diffraction and electron microscopy reveal ubiquitous antisite defects in both cation sites and, possibly, Mn vacancies. Powders of MnBi$_{2}$Te$_{4}$ can be obtained at subsolidus temperatures, and a complementary thermochemical study establishes a limited high-temperature range of phase stability. Nevertheless, quenched powders are stable at room temperature and exhibit long-range antiferromagnetic ordering below 24 K. The expected Mn(II) out-of-plane magnetic state is confirmed by the magnetization, X-ray photoemission, X-ray absorption and linear dichroism data. MnBi$_{2}$Te$_{4}$ exhibits a metallic type of resistivity in the range 4.5-300 K. The compound is an n-type conductor that reaches a thermoelectric figure of merit up to ZT = 0.17. Angle-resolved photoemission experiments provide evidence for a surface state forming a gapped Dirac cone.

---
Source: https://tomesphere.com/paper/1812.03106