# Effect of (Cu/Fe)O5 bipyramid size and separation on magnetic and dielectric properties of rare earth layered perovskite LaBaCuFeO5 and LuBaCuFeO5

## TL;DR

This study investigates how the size and separation of bipyramids in layered perovskites LaBaCuFeO5 and LuBaCuFeO5 influence their magnetic and dielectric properties, revealing distinct multiglass behaviors linked to structural differences.

## Contribution

It provides new insights into the relationship between bipyramid size, structural modifications, and multiglass phenomena in layered perovskite materials.

## Key findings

- LaBaCuFeO5 exhibits magnetic cluster glass behavior below 60 K.
- LuBaCuFeO5 shows a magnetic transition at 175 K and strong spin anisotropy.
- Different behaviors are due to structural variations from ionic radii differences.

## Abstract

We report structural, magnetic and dielectric properties of layered perovskite materials LnBaCuFeO5 (Ln = La and Lu). LaBaCuFeO5 shows magnetic cluster glass behavior below 60 K owing to the competing ferromagnetic and antiferromagnetic exchange interactions. Glassy dynamics of electric dipoles has also been observed in the vicinity of the magnetic glass transition temperature. The presence of significant coupling between spin and polar degrees of freedom results in the multiglass feature in LaBaCuFeO5. The LuBaCuFeO5 compound undergoes YBaCuFeO5 like commensurate to incommensurate antiferromagnetic transition at 175 K. Large magnetic irreversibility below 17 K in this compound suggests the presence of strong spin anisotropy. In addition, in this compound the interaction between the dipoles is not strong enough, which results in the absence of glassy dynamics of electric dipoles. The contrasting behavior of two compounds is possibly due to variation in the ferromagnetic and antiferromagnetic interactions along c-axis, which is the manifestation of structural modification arising out of the difference in the ionic radii of La and Lu.

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Source: https://tomesphere.com/paper/1812.01239