Analysis of the magnetic and magnetocaloric properties of ALaFeMnO6 (A= Sr, Ba and Ca) double perovskites

TL;DR

This study investigates the magnetic and magnetocaloric properties of ALaMnFeO6 (A= Sr, Ba, Ca) double perovskites, revealing how A-site substitution influences structure, magnetic transition temperatures, and potential for room-temperature cooling applications.

Contribution

It provides new insights into how A-site substitution in La2MnFeO6-based double perovskites affects their structure, magnetic properties, and magnetocaloric effects, expanding their potential for practical cooling devices.

Findings

Sr substitution increases Curie temperature up to 350 K.

Ba and Sr lead to rhombohedral structures, Ca maintains orthorhombic.

Sr-doped sample shows significant magnetocaloric effect above 300 K.

Abstract

In previous studies, we have reported that double perovskite La2NiMnO6 presents a non-negligible potential for room temperature magnetocaloric tasks. With the aim of improving even further the cooling performances and the working temperature range of double perovskites, we report the magnetic and magnetocaloric properties of La2MnFeO6 and ALaMnFeO6 (A = Sr, Ba, Ca) compounds. X-ray diffraction (XRD) and Rietveld refinement show that La2MnFeO6 (LMFO) and CaLaMnFeO6 (CLMFO) samples crystallize in an orthorhombic structure with the Pnma space group. However, a rhombohedral structure with the R3C space group is obtained for BaLaMnFeO6 (BLMFO) and SrLaMnFeO6 (SLMFO) samples. Substituting La by Ba or Sr in LMFO leads to a clear increase of the Curie temperature (Tc) compared to LMFO from 150 K for BLMFO up to 350 K for SLMFO. Moreover, CLMFO shows the smallest Tc down to 70 K. Ferromagnetic-like behavior is observed for SLMFO and BLMFO while CLMFO's magnetism resembles that of LMFO. A clear connection between the structural parameters and the magnetic properties of these doped LMFO samples is unveiled as the highest Tc and the largest magnetization are observed for SLMFO which shows also bond angles closest to 180{\deg} and the smallest bond lengths, thus optimizing the superexchange interaction. The partial substitution of Sr for La leads in fact to a significant magnetocaloric effect over a wide operating temperature range extending beyond 300 K. For some optimal growth conditions, its entropy change varies slowly over an unusually large temperature range, which is of clear interest from a practical point of view.