Hopping conductance and macroscopic quantum tunneling effect in three dimensional Pb$_x$(SiO$_2$)$_{1-x}$ nanogranular films

TL;DR

This study investigates low-temperature electrical transport in Pb$_x$(SiO$_2$)$_{1-x}$ nanogranular films, revealing hopping conduction and quantum tunneling effects, with a focus on how composition influences superconducting and transport properties.

Contribution

It provides a comprehensive analysis of the transition from electron hopping to Josephson coupling in nanogranular films across different compositions, including quantum phase slip effects.

Findings

Resistivity follows exponential behavior below $T_c$ for certain compositions.

Negative magnetoresistance indicates single electron tunneling dominates below $T_c$.

Quantum phase slips explain resistivity behavior in highly conductive films.

Abstract

We have studied the low-temperature electrical transport properties of Pb$_x$(SiO$_2$)$_{1-x}$ ($x$ being the Pb volume fraction) nanogranular films with thicknesses of $\sim$1000 nm and $x$ spanning the dielectric, transitional, and metallic regions. It is found that the percolation threshold $x_c$ lies between 0.57 and 0.60. For films with $x$$\lesssim$0.50, the resistivities $\rho$ as functions of temperature $T$ obey $\rho\propto\exp(\Delta/k_BT)$ relation ($\Delta$ being the local superconducting gap and the $k_B$ Boltzmann constant) below the superconducting transition temperature $T_c$ ($\sim$7 K) of Pb granules. The value of the gap obtained via this expression is almost identical to that by single electron tunneling spectra measurement. The magnetoresistance is negative below $T_c$ and its absolute value is far larger than that above $T_c$ at a certain field. These observations indicate that single electron hopping (or tunneling), rather than Cooper pair hopping (or tunneling) governs the transport processes below $T_c$. The temperature dependence of resistivities shows reentrant behavior for the 0.50$<$$x$$<$0.57 films. It is found that single electron hopping (or tunneling) also dominates the low-temperature transport process for these films. The reduction of the single electron concentration leads to an enhancement of the resisivity at sufficiently low temperature. For the 0.60$\lesssim$$x$$\lesssim$0.72 films, the resistivities sharply decrease with decreasing temperature just below $T_c$, and then show dissipation effect with further decreasing temperature. Treating the conducting paths composed of Pb particles as nanowires, we have found that the $R(T)$ data below $T_c$ can be well explained by a model that includes both thermally activated phase slips and quantum phase slips.