Ultrafast insulator-to-metal transition in VO$_2$ nanostructures assisted by picosecond strain pulses

TL;DR

This study demonstrates that picosecond strain pulses can control the ultrafast insulator-to-metal phase transition in VO$_2$ nanostructures, enabling potential ultrafast strain engineering at THz frequencies.

Contribution

It introduces a method to manipulate phase transitions in nanostructures using synchronized ultrafast strain pulses and optical excitation, a novel approach in strain engineering.

Findings

Strain pulses can modulate the fraction of VO$_2$ undergoing phase transition.

Transient strain affects non-thermal photo-induced phase changes but not thermal ones.

Ultrafast strain control is effective during non-thermal phase transitions.

Abstract

Strain engineering is a powerful technology which exploits stationary external or internal stress of specific spatial distribution for controlling the fundamental properties of condensed materials and nanostructures. This advanced technique modulates in space the carrier density and mobility, the optical absorption and, in strongly correlated systems, the phase, e.g. insulator/metal or ferromagnetic/paramagnetic. However, while successfully accessing nanometer length scale, strain engineering is yet to be brought down to ultrafast time scales allowing strain-assisted control of state of matter at THz frequencies. In our work we demonstrate a control of an optically-driven insulator-to-metal phase transition by a picosecond strain pulse, which paves a way to ultrafast strain engineering in nanostructures with phase transitions. This is realized by simultaneous excitation of VO$_2$ nanohillocks by a 170-fs laser and picosecond strain pulses finely timed with each other. By monitoring the transient optical reflectivity of the VO$_2$, we show that strain pulses, depending on the sign of the strain at the moment of optical excitation, increase or decrease the fraction of VO$_2$ which undergoes an ultrafast phase transition. Transient strain of moderate amplitude $\sim0.1$% applied during ultrafast photo-induced non-thermal transition changes the fraction of VO$_2$ in the laser-induced phase by $\sim1$%. By contrast, if applied after the photo-excitation when the phase transformations of the material are governed by thermal processes, transient strain of the same amplitude produces no measurable effect on the phase state.