Spectral redshift of the thermal near field scattered by a probe

TL;DR

This paper investigates the spectral redshift of thermally generated surface phonon-polaritons in near-field thermal spectroscopy, revealing the physical mechanisms and the importance of accurate modeling for interpreting spectral shifts.

Contribution

It demonstrates that the spectral redshift is caused by electromagnetic gap modes and shows that simplified models like dipole approximations are insufficient, emphasizing the need for exact simulations.

Findings

Maximum redshift of 19 cm-1 predicted for specific probe and gap conditions

Redshift is mediated by electromagnetic gap modes in the vacuum gap

Sharp tips cause spectral broadening of the scattered field

Abstract

The physics underlying spectral redshift of thermally generated surface phonon-polaritons (SPhPs) observed in near-field thermal spectroscopy is investigated. Numerically exact fluctuational electrodynamics simulations of the thermal near field emitted by a silicon carbide surface scattered in the far zone by an intrinsic silicon probe show that SPhP resonance redshift is a physical phenomenon. A maximum SPhP redshift of 19 cm-1 is predicted for a 200-nm-diameter hemispherical probing tip and a vacuum gap of 10 nm. Resonance redshift is mediated by electromagnetic gap modes excited in the vacuum gap separating the probe and the surface when the probing tip is much larger than the gap size. The impact of gap modes on the scattered field can be mitigated with a probing tip size approximately equal to or smaller than the vacuum gap. However, sharp probing tips induce important spectral broadening of the scattered field. It is also demonstrated that a dipole approximation with multiple reflections cannot be used for explaining the physics and predicting the amount of redshift in near-field thermal spectroscopy. This work shows that the scattered field in the far zone is a combination of the thermal near field emitted by the surface, and electromagnetic interactions between the probe and the surface. Spectroscopic analysis of near-field thermal emission thus requires a numerically exact fluctuational electrodynamics framework for modeling probe-surface interactions.