Surface Plasmon Resonance in a metallic nanoparticle embedded in a semiconductor matrix: exciton-plasmon coupling

TL;DR

This paper models the electromagnetic coupling between surface plasmons in metallic nanoparticles and excitons or electron-hole pairs in a semiconductor matrix, deriving an expression for the nanoparticle polarizability and analyzing Fano resonances.

Contribution

It introduces a new theoretical expression for nanoparticle polarizability considering exciton-plasmon coupling and applies it to fit experimental spectra.

Findings

Derived a renormalized polarizability expression accounting for exciton-plasmon interaction.

Identified conditions for Fano-type resonances in nanoparticle-semiconductor systems.

Successfully fitted experimental LSPR lineshape in gold NPs embedded in CuO.

Abstract

We consider the effect of electromagnetic coupling between localized surface plasmons in a metallic nanoparticle (NP) and excitons or weakly interacting electron-hole pairs in a semiconductor matrix where the NP is embedded. An expression is derived for the NP polarizability renormalized by this coupling and two possible situations are analyzed, both compatable with the conditions for Fano-type resonances: (i) a narrow bound exciton transition overlapping with the NP surface plasmon resonance (SPR), and (ii) SPR overlapping with a parabolic absorption band due to electron-hole transitions in the semiconductor. The absorption band lineshape is strongly non-Lorentzian in both cases and similar to the typical Fano spectrum in the case (i). However, it looks differently in the situation (ii) that takes place for gold NPs embedded in a CuO film and the use of the renormalized polarizability derived in this work permits to obtain a very good fit to the experimentally measured LSPR lineshape.