Synthesis, structural and photo physical properties of perovskite oxide (KNbO3)1-X+(La2NiMnO6)X for photovoltaic application

TL;DR

This study explores the synthesis and characterization of KNbO3-La2NiMnO6 solid solutions with tunable band gaps, structural changes, and optical properties, highlighting their potential as photovoltaic materials.

Contribution

It introduces a new class of perovskite oxide solid solutions with adjustable band gaps and structural properties suitable for photovoltaic applications.

Findings

Band gap of 1.33 eV in x=0.1 matches Shockley-Queisser limit

Structural transition from orthorhombic to cubic with doping

Significant photoluminescence quenching observed

Abstract

Solid solutions of perovskite oxides (KNbO3)1-x+(La2NiMnO6)x (x=0, 0.1, 0.2 and 0.3) with a variation of band gap (1.33-3.6 eV) have been introduced as a promising photovoltaic absorber. The structural characterization of the prepared samples was carried out using X-ray diffraction (followed by Rietveld refinement) and Raman experiment. As the doping percentage of the monoclinic La2NiMnO6 in the solid-solution increases, the crystal structure of host KNbO3 becomes more symmetric from orthorhombic to cubic. A large reduction in the particle size has also been observed in the solid solutions in comparison to the pure KNbO3. The band gap (~ 1.33 eV) of the synthesized solid solution x=0.1 is found to be very close to the Shockley-Queisser band gap value of 1.34 eV, which suggests the promising photovoltaic possibility in this material. Photoluminescence (PL) emission spectra reveal a strong PL quenching in the solid-solutions in comparison to the KNbO3. The overall structural and optical studies suggest the promising photovoltaic possibility in KNbO3/ La2NiMnO6 solid solution.