Morphometric approach to many-body correlations in hard spheres

TL;DR

This paper introduces a morphometric method to model many-body correlations in hard sphere liquids, accurately predicting free energies and revealing structural bimodality and relaxation barriers across different regimes.

Contribution

The study presents a novel morphometric approach to calculate local structure thermodynamics in hard sphere liquids, extending analysis into supercooled states.

Findings

Excellent agreement with molecular dynamics simulations.

Identification of bimodal density library with structural free energy differences.

Prediction of relaxation barriers scaling linearly with compressibility.

Abstract

We model the thermodynamics of local structures within the hard sphere liquid at arbitrary volume fractions through the \textit{morphometric} calculation of $n$-body correlations. We calculate absolute free energies of local geometric motifs in excellent quantitative agreement with molecular dynamics simulations across the liquid and supercooled liquid regimes. We find a bimodality in the density library of states where five-fold symmetric structures appear lower in free energy than four-fold symmetric structures, and from a single reaction path predict a relaxation barrier which scales linearly in the compressibility factor. The method provides a new route to assess changes in the free energy landscape at volume fractions dynamically inaccessible to conventional techniques.