A versatile lattice Boltzmann model for immiscible ternary fluid flows

TL;DR

This paper introduces a versatile lattice Boltzmann model for simulating immiscible ternary fluid flows, capable of handling a full range of interfacial tensions and critical states with high accuracy.

Contribution

The paper develops a novel lattice Boltzmann color-gradient model with an improved interfacial force and segregation algorithm for accurate ternary fluid flow simulation.

Findings

Successfully reproduces seven equilibrium morphologies.

Accurately simulates Janus droplets with Neumann's triangle conditions.

Effectively models near-critical and critical states of double droplets.

Abstract

We propose a lattice Boltzmann color-gradient model for immiscible ternary fluid flows, which is applicable to the fluids with a full range of interfacial tensions, especially in near-critical and critical states. An interfacial force for N-phase systems is derived based on the previously developed perturbation operator and is then introduced into the model using a body force scheme, which helps reduce spurious velocities. A generalized recoloring algorithm is applied to produce phase segregation and ensure immiscibility of three different fluids, where a novel form of segregation parameters is proposed by considering the existence of Neumann's triangle and the effect of equilibrium contact angle in three-phase junction. The proposed model is first validated with three typical examples, namely the interface capturing for two separate static droplets, the Young-Laplace test for a compound droplet, and the spreading of a droplet between two stratified fluids. This model is then used to study the structure and stability of double droplets in a static matrix. Consistent with the theoretical stability diagram, seven possible equilibrium morphologies are successfully reproduced by adjusting two ratios of the interfacial tensions. By simulating Janus droplets in various geometric configurations, the model is shown to be accurate when three interfacial tensions satisfy a Neumann's triangle. In addition, we also simulate the near-critical and critical states of double droplets where the outcomes are very sensitive to the model accuracy. Our results show that the present model is advantageous to three-phase flow simulations, and allows for accurate simulation of near-critical and critical states.