Additive Manufacturing and Characterization of Architectured Cement-based Materials via X-ray Micro-Computed Tomography

TL;DR

This study uses X-ray micro-CT to analyze the microstructure of 3D-printed cement-based materials, revealing patterned pore networks and heterogeneities induced by additive manufacturing processes.

Contribution

It introduces a modified 3D printing process combined with micro-CT analysis to characterize microstructural features and heterogeneities in architectured cement-based materials.

Findings

Patterned pore networks in 3D-printed specimens

Comparison shows cast specimens have randomly distributed pores

Micro-CT effectively characterizes processing-induced heterogeneities

Abstract

There is an increasing interest in the fabrication of cement-based materials via additive manufacturing (AM) techniques. However, the processing-induced heterogeneities and interfaces represent a major challenge. The role of processing in creating interfaces and their characteristics requires understanding of the microstructure of 3D-printed hardened cement paste (hcp). This work investigates the microstructural features of architectured cement-based materials, including processing-induced heterogeneous patterns, interfacial regions (IRs), and pore network distributions with respect to the architectural pattern. A 3D printer was modified and merged with an extrusion system and specimens were 3D-printed using a layer-wise direct ink writing (DIW) process capable of fabrication of lamellar architectures of materials. A lab-based X-ray microscope (XRM) was used to perform X-ray micro-computed tomography (micro-CT) evaluations to explore the microstructural characteristics of 3-day old intact (i.e. not tested) 3D printed and cast specimens at two levels of magnification: 0.4X and 4X. CT scans of printed specimen revealed a patterned pore network and several microstructural features, including: a) macropores, b) micropores at interfacial regions (IRs), c) accumulation of anhydrous cement particles near macropores, and d) rearrangement of filaments away from their designed toolpath. In comparison, microstructural investigation of cast specimen at 4X scan revealed randomly distributed pores with no connectivity throughout the specimen. The aptitude of micro-CT as a non-destructive technique for microstructural characterization is discussed. The role of processing to induce and to pattern heterogeneities such as IRs in materials is demonstrated and the role of architecture in controlling such heterogeneities and their directionality through the interface is discussed.