Quantum hydrodynamics for nanoplasmonics

TL;DR

This paper demonstrates how quantum hydrodynamics (QHD) can effectively model nanoplasmonic phenomena, capturing quantum effects in metallic nanoshells more efficiently than traditional ab-initio methods like TD-DFT.

Contribution

The paper applies QHD to model plasmonic oscillations in nanoshells and compares its results with TD-DFT, highlighting its advantages for nanoplasmonics.

Findings

QHD captures quantum and nonlinear effects in plasmonic nanoshells.

QHD results are systematically comparable to TD-DFT.

QHD offers a computationally efficient alternative for nanoplasmonic modeling.

Abstract

Quantum effects play a significant role in nanometric plasmonic devices, such as small metal clusters and metallic nanoshells. For structures containing a large number of electrons, ab-initio methods such as the time-dependent density functional theory (TD-DFT) are often impractical because of severe computational constraints. Quantum hydrodynamics (QHD) offers a valuable alternative by representing the electron population as a continuous fluid medium evolving under the action of the self-consistent and external fields. Although relatively simple, QHD can incorporate quantum and nonlinear effects, nonlocal effects such as the electron spillout, as well as exchange and correlations. Here, we show an application of the QHD methods to the plasmonic breathing oscillations in metallic nanoshells. We illustrate the main advantages of this approach by comparing systematically the QHD results with those obtained with a TD-DFT code.