Influence of interface-driven strain on the spectral diffusion properties of core/shell CdSe/CdS dot/rod nanoparticles

TL;DR

This study combines atomistic and effective-mass calculations to show how strain affects the electronic and spectral diffusion properties of CdSe/CdS dot/rod nanoparticles, revealing increased energy shifts and wave function changes due to strain.

Contribution

It provides a detailed analysis of strain effects on band alignment and excitonic properties, highlighting their impact on spectral diffusion in core/shell nanoparticles.

Findings

Strain increases exciton energy and reduces wave function overlap.

Native type-I band alignment is preserved despite strain.

Strain amplifies spectral diffusion effects related to surface charges.

Abstract

By combining an atomistic valence-force field approach and calculations based on the effective-mass approximation we investigate the influence of strain effects on the band alignment and general excitonic properties of core/shell CdSe/CdS dot/rod nanoparticles. We find that the inclusion of strain effects leads to an increase in exciton energy as well as to a decrease in electron and hole wave function overlap. Importantly, the native type-I band alignment of the CdSe/CdS material system is preserved and does not change into an quasi-type-II or even type-II band offset for the nanoparticles. Furthermore, we analyze the impact of strain on a model in which the spectral diffusion of the fluorescence emission of these nanoparticles is explained by migrating surface charges. Our calculations show that the addition of strain effects leads to increased energy shifts as well as larger changes in the squared electron and hole wave function overlap, while the correlation of both also exhibits a steeper slope than for the unstrained system. For a given CdSe core size, an increase in CdS-shell thickness decreases the possible ranges of energy shift and squared wave function overlap without changing the slope of their correlation. On the other hand, for a given nanoparticle overall thickness, dot/rod systems with a small CdSe core exhibit the strongest influenceability by surface charges.