Von Neumann entropy from unitarity
P. Boes, J. Eisert, R. Gallego, M. P. Mueller, H. Wilming

TL;DR
This paper offers a new operational perspective on von Neumann entropy, linking it to single-shot state transitions in unitary quantum mechanics with catalysts and decoherence, challenging traditional asymptotic interpretations.
Contribution
It introduces a novel characterization of von Neumann entropy applicable in single-shot scenarios without i.i.d. assumptions or explicit randomness, and explores the catalytic entropy conjecture.
Findings
Von Neumann entropy characterizes single-shot state transitions with catalysts.
Evidence supporting the catalytic entropy conjecture in the presence of decoherence.
Implications for quantum thermodynamics and holography discussed.
Abstract
The von Neumann entropy is a key quantity in quantum information theory and, roughly speaking, quantifies the amount of quantum information contained in a state when many identical and independent i.i.d. copies of the state are available, in a regime that is often referred to as being asymptotic. In this work, we provide a new operational characterization of the von Neumann entropy which neither requires an i.i.d. limit nor any explicit randomness. We do so by showing that the von Neumann entropy fully characterizes single-shot state transitions in unitary quantum mechanics, as long as one has access to a catalyst - an ancillary system that can be re-used after the transition - and an environment which has the effect of dephasing in a preferred basis. Building upon these insights, we formulate and provide evidence for the catalytic entropy conjecture, which states that the above result…
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