Low Temperature Combustion Synthesis of a Spinel NiCo2O4 Hole Transport Layer for Perovskite Photovoltaics

TL;DR

This paper presents a low-temperature solution process for synthesizing NiCo2O4 nanoparticles used as an efficient hole transport layer in perovskite solar cells, achieving high efficiency and smooth film quality.

Contribution

It introduces a novel combustion synthesis method for NiCo2O4 nanoparticles and demonstrates their effective application as a hole transport layer in perovskite photovoltaics.

Findings

Achieved 15.5% power conversion efficiency with NiCo2O4 HTL.

Optimized 15 nm NiCo2O4 layer improves hole collection.

Produced smooth, homogeneous HTL films via blade coating.

Abstract

In the present study, we report the synthesis and characterization of a low-temperature solution-processable monodispersed nickel cobaltite (NiCo2O4) nanoparticles via a combustion synthesis using tartaric acid as fuel and demonstrate its performance as hole transport layer (HTL) for Perovskite Solar Cells (PVSCs). NiCo2O4 is a p-type semiconductor consisting of environmentally friendly, abundant elements and higher conductivity compared to NiO. We show that the combustion synthesis of spinel NiCo2O4 using tartaric acid as fuel can be used to control the NPs size and provide smooth, compact and homogeneous functional HTLs processed by blade coating. Study of PVSCs with different NiCo2O4 thickness as HTL reveal a difference on hole extraction efficiency and for 15 nm optimized thickness enhanced hole carrier collection is achieved. As a result, p-i-n structure of PVSCs with 15 nm NiCo2O4 HTLs showed reliable performance and power conversion efficiency values in the range of 15.5 % with negligible hysteresis.