Spectrally Resolved Mid-Infrared Molecular Emission from Protoplanetary Disks and the Chemical Fingerprint of Planetesimal Formation
Joan R. Najita, John S. Carr, Colette Salyk, John H. Lacy, Matthew J., Richter, and Curtis DeWitt

TL;DR
This study uses high-resolution mid-infrared spectroscopy to analyze molecular emissions from protoplanetary disks, revealing chemical signatures linked to planetesimal formation and providing insights into disk chemistry and molecular excitation.
Contribution
First spectrally resolved mid-infrared HCN line profiles from protoplanetary disks, linking molecular emissions to planetesimal formation processes.
Findings
HCN and water emissions originate within 1-2 AU of the star.
The HCN/water emission ratio increases with disk mass, indicating chemical evolution.
HCN line profiles are similar in mid- and near-infrared, challenging existing excitation models.
Abstract
We present high resolution spectroscopy of mid-infrared molecular emission from two very active T Tauri stars, AS 205 N and DR Tau. In addition to measuring high signal-to-noise line profiles of water, we report the first spectrally resolved mid-infrared line profiles of HCN emission from protoplanetary disks. The similar line profiles and temperatures of the HCN and water emission indicate that they arise in the same volume of the disk atmosphere, within 1-2AU of the star. The results support the earlier suggestion that the observed trend of increasing HCN/water emission with disk mass is a chemical fingerprint of planetesimal formation and core accretion in action. In addition to directly constraining the emitting radii of the molecules, the high resolution spectra also help to break degeneracies between temperature and column density in deriving molecular abundances from low…
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