Streamer evolution arrest governed amplified AC breakdown strength of graphene and CNT colloids

TL;DR

This study demonstrates that adding trace amounts of graphene or CNTs to mineral oils significantly enhances their AC dielectric breakdown strength by delaying streamer development, with a 70-80% improvement and a validated electron scavenging model.

Contribution

It introduces a novel nano-oil formulation with nanostructures that improve dielectric strength and reliability, supported by a quantitative electron scavenging model.

Findings

70-80% increase in breakdown voltage

Enhanced reliability and survival probabilities

Validated electron scavenging mechanism

Abstract

The present article experimentally explores the concept of large improving the AC dielectric breakdown strength of insulating mineral oils by the addition of trace amounts of graphene or CNTs to form stable dispersions. The nano-oils infused with these nanostructures of high electronic conductance indicate superior AC dielectric behaviour in terms of augmented breakdown strength compared to the base oils. Experimental observations of two grades of synthesized graphene and CNT nano-oils show that the nanomaterials not only improve the average breakdown voltage but also significantly improve the reliability and survival probabilities of the oils under AC high voltage stressing. Improvement of the tune of ~ 70-80 % in the AC breakdown voltage of the oils has been obtained via the present concept. The present study examines the reliability of such nano-colloids with the help of two parameter Weibull distribution and the oils show greatly augmented electric field bearing capacity at both standard survival probability values of 5 % and 63.3 %. The fundamental mechanism responsible for such observed outcomes is reasoned to be delayed streamer development and reduced streamer growth rates due to effective electron scavenging by the nanostructures from the ionized liquid insulator. A mathematical model based on the principles of electron scavenging is proposed to quantify the amount of electrons scavenged by the nanostructures. The same is then employed to predict the enhanced AC breakdown voltage and the experimental values are found to match well with the model predictions. The present study can have strong implications in efficient, reliable and safer operation of real life AC power systems.