Enhanced radiation tolerance of YSZ at high temperature against swift heavy ions: key role of interplay between material microstructure and irradiation temperature

TL;DR

This study demonstrates that high irradiation temperature enhances the radiation tolerance of YSZ, especially in nano-crystalline forms, due to the interplay between microstructure and temperature effects on thermal spike dynamics.

Contribution

It reveals how irradiation temperature and crystallite size jointly influence radiation damage in YSZ, supported by theoretical modeling of thermal spike effects.

Findings

Nano-crystalline YSZ suffers more damage at room temperature.

Irradiation at 1000 K reduces damage across all samples.

Nano-crystalline samples show significantly improved tolerance at high temperature.

Abstract

Yttria stabilized Zirconia (YSZ) pellets with different crystallite sizes were irradiated with 80 MeV Ag$^{6+}$ ions at room temperature and 1000 K to understand the role of crystallite size/material microstructure and irradiation temperature on the radiation tolerance against high electronic energy loss (S$_e$). X-ray diffraction and Raman spectroscopy measurements reveal that, irrespective of the irradiation temperature, the nano-crystalline samples suffered more damage as compared to the bulk-like sample. A reduction in the irradiation damage i.e. improvement in the radiation tolerance, was observed for all the samples irradiated at 1000 K. The reduction in the damage, however, was remarkably higher for the two nano-crystalline samples compared to the bulk-like sample, and hence the difference in the damage between the bulk-like and nano-crystalline samples was also significantly lower at 1000 K than that at room temperature. The irradiation damage, against S$_e$, was thus found to be critically dependent on the interplay between the irradiation temperature and crystallite size. These results are explained with the help of detailed theoretical calculations/simulations based on the 'in-elastic thermal spike' model by taking into consideration the combined effect of crystallite size and environmental (irradiation) temperature on the electron-phonon coupling factor and lattice thermal conductivity (and hence on the resulting thermal spike). Our results are crucial from the fundamental perspective of comprehending the size and temperature dependent radiation damage against S$_e$ ; and also for a number of applications, in various radiation environments, where nano-materials are being envisioned for use.