Tunable disorder and localization in the rare-earth nickelates

TL;DR

This study investigates how tunable disorder via irradiation affects transport and localization in LaNiO3, revealing a metal-insulator transition, non-Fermi liquid behavior, and Anderson localization, demonstrating irradiation as a tool to control electronic properties.

Contribution

It introduces ion irradiation as a method to tune disorder in rare-earth nickelates and explores the resulting localization phenomena and metal-insulator transition.

Findings

Irradiation induces a transition from metallic to insulating behavior.

High-temperature metallic regime shows a shift from non-Fermi liquid to Fermi-liquid-like behavior.

Insulating samples exhibit weak localization and variable range hopping consistent with Anderson localization.

Abstract

The rare-earth nickelates are a rich playground for transport properties, known to host non-Fermi liquid character, resistance saturation and metal-insulator transitions. We report a study of transport in LaNiO3 in the presence of tunable disorder induced by irradiation. While pristine LaNiO3 samples are metallic, highly irradiated samples show insulating behaviour at all temperatures. Using irradiation fluence as a tuning handle, we uncover an intermediate region hosting a metal-insulator transition. This transition falls within the Mott-Ioffe-Regel regime wherein the mean free path is comparable to lattice spacing. In the high temperature metallic regime, we find a transition from non-Fermi liquid to a Fermi-liquid-like character. On the insulating side of the metal-insulator transition, we find behaviour that is consistent with weak localization. This is reflected in magnetoresistance that scales with the square of the field and in resistivity. In the highly irradiated insulating samples, we find good agreement with variable range hopping, consistent with Anderson localization. We find qualitatively similar behaviour in thick PrNiO3 films as well. Our results demonstrate that ion irradiation can be used to tailor transport, serving as an excellent tool to study the physics of localization.