Drag Coefficient of a Circular Inclusion in a Near-Critical Binary Fluid Membrane

TL;DR

This paper calculates how the drag coefficient of a circular domain in a near-critical binary fluid membrane is affected by preferential attraction and viscosity differences, providing analytical and numerical insights into the dynamics near criticality.

Contribution

It introduces a theoretical framework to evaluate the drag coefficient considering preferential attraction effects in near-critical binary fluid membranes.

Findings

The first-order approximation is often sufficient for practical parameters.

Preferential attraction can significantly influence the drag coefficient.

High domain viscosity diminishes the effect of preferential attraction.

Abstract

We calculate the drag coefficient of a circular liquid domain, which is put in a flat fluid membrane composed of a binary fluid mixture lying in the homogeneous phase near the demixing critical point. Assuming a sufficiently small correlation length, we regard the domain dynamics as independent of the critical fluctuation and use the Gaussian free-energy functional for the mixture. Because of the near-criticality, the preferential attraction between the domain component and one of the mixture components generates the composition gradient outside the domain significantly and can affect the drag coefficient. We first consider a domain having the same membrane viscosity as the domain exterior. The drag coefficient is expanded with respect to a dimensionless strength of the preferential attraction. It is numerically shown that the magnitude of the expansion coefficient decreases much as the order of the strength increases and that the first-order term of the series usually gives a good approximation for practical material constants. The effect of the preferential attraction is shown to be able to become significantly large in practice. We second consider cases where the membrane viscosities of the domain interior and exterior are different. The first-order term of the expansion series decreases to approach zero as the domain viscosity increases to infinity. This agrees with previous numerical results showing that the hydrodynamics makes the effect of the preferential attraction negligibly small for a rigid disk.