Magnetohydrodynamics and magneto-solutal transport mediated evaporation dynamics in paramagnetic pendent droplets under field stimulus

TL;DR

This study investigates how magnetic fields influence evaporation in paramagnetic droplets by enhancing internal flow via magneto-solutal and magnetothermal effects, combining experiments and modeling to reveal dominant advection mechanisms.

Contribution

It introduces a comprehensive analytical model incorporating magneto-thermosolutal effects and validates it with experimental data, advancing understanding of magnetically modulated droplet evaporation.

Findings

Magnetic field increases evaporation rate proportionally to magnetic ion moment.

Internal flow within droplets is intensified and reoriented by magnetic influence.

Model accurately predicts internal circulation velocities and highlights magneto-solutal advection as key factor.

Abstract

Evaporation kinetics of pendant droplets is an area of immense importance in several applications in addition to possessing rich fluid and thermal transport physics. The present article experimentally and analytically sheds insight into the augmented evaporation dynamics of paramagnetic pendent droplets in the presence of a magnetic field stimulus. Literature provides information that solutal advection and solutal Marangoni effect lead to enhancement of evaporation in droplets with ionic inclusions. The major crux of the present article remains to modulate the thermosolutal advection with the aid of magnetic field and comprehend the dynamics of the evaporation process under such complex multiphysics interactions. Experimental observations reveal that the evaporation rate enhances as a direct function of the magnetic moment of the solvated magnetic element ions, thereby pinpointing at the magnetophoretic and magneto-solutal advection. Additionally, flow visualization by PIV illustrates that the internal advection currents within the droplet are strengthened in magnitude as well as distorted in orientation by the magnetic field. A mathematical formalism based on magnetothermal and magnetosolutal advection effects has been proposed via scaling analysis of the species and energy conservation equations. The formalism takes into account all major governing factors such as the magnetothermal and magnetosolutal Marangoni numbers, magneto Prandtl and magneto Schmidt numbers and the Hartmann number. The modeling establishes the magnetosolutal advection component to be the domineering factor in augmented evaporation dynamics. Accurate validation of the experimental internal circulation velocity is obtained from the proposed model. The present study reveals rich insight on the magneto thermosolutal hydrodynamics aspects in paramagnetic droplets.