Breaking the fundamental energy dissipation limit in ferroelectric-dielectric capacitors

TL;DR

This paper demonstrates that coupling a ferroelectric to a dielectric capacitor can surpass the fundamental 50% energy dissipation limit during charging, enabling more efficient energy storage by recycling phase transition energy.

Contribution

The study introduces a method to break the fundamental energy dissipation limit in capacitors through ferroelectric coupling, supported by solving Maxwell's equations for the system.

Findings

Energy dissipation during charging is reduced below 50%.

Energy is recycled via ferroelectric phase transitions.

Direct energy transfer occurs between ferroelectric and dielectric.

Abstract

Half of the energy is always lost when charging a capacitor. Even in the limit of vanishing resistance, half of the charging energy is still lost--to radiation instead of heat. While this fraction can technically be reduced by charging adiabatically, it otherwise places a fundamental limit on the charging efficiency of a capacitor. Here we show that this 1/2 limit can be broken by coupling a ferroelectric to the capacitor dielectric. Maxwell's equations are solved for the coupled system to analyze energy flow from the perspective of Poynting's theorem and show that (1) total energy dissipation is reduced below the fundamental limit during charging and discharging; (2) energy is saved by "recycling" the energy already stored in the ferroelectric phase transition; and (3) this phase transition energy is directly transferred between the ferroelectric and dielectric during charging and discharging. These results demystify recent works on low energy negative capacitance devices as well as lay the foundation for improving fundamental energy efficiency in all devices that rely on energy storage in electric fields.