Lattice distortion effects on the frustrated spin-1 triangular-antiferromagnet A3NiNb2O9 (A = Ba, Sr and Ca)

TL;DR

This study investigates how lattice distortions in S=1 triangular antiferromagnets A3NiNb2O9 affect their magnetic properties, revealing changes in magnetic ground states and excitations due to structural modifications.

Contribution

It provides the first detailed analysis of lattice distortion effects on S=1 TLAFs, combining experimental measurements with theoretical simulations.

Findings

Lattice distortion changes the triangle shape from equilateral to isosceles.

The magnetic ground state remains a 120° antiferromagnetic phase.

Neutron scattering data align with linear spin-wave theory simulations.

Abstract

In the geometrically frustrated materials with the low-dimensional and small spin moment, the quantum fluctuation could interfere with the complicated interplay of the spin, electron, lattice and orbital interactions, and host exotic ground states such as nematic spin-state and chiral liquid phase. While the quantum phases of the one-dimensional chain and S - 1/2 two-dimensional triangular-lattice antiferromagnet (TLAF) had been more thoroughly investigated by both theorists and experimentalists, the work on S = 1 TLAF has been limited. We induced the lattice distortion into the TLAFs, A3NiNb2O9 (A = Ba, Sr, and Ca) with S (Ni2+) = 1, and applied the thermodynamic, magnetic and neutron scattering measurements. Although A3NiNb2O9 kept the non-collinear 120{\deg} antiferromagnetic phase as the ground state, the Ni2+-lattice changed from the equilateral triangle (A = Ba) into isosceles triangle (A = Sr and Ca). The inelastic neutron scattering data were simulated by the linear spin-wave theory, and the competition between the single-ion anisotropy and the exchange anisotropy from the distorted lattice was discussed.