The Effect of Water on Quinone Redox Mediators in Non- aqueous Li-O2 Batteries

TL;DR

This study demonstrates that water enhances the performance of non-aqueous Li-O2 batteries by stabilizing quinone mediators, enabling larger Li2O2 crystals, and promoting a solution-based discharge process, leading to higher capacity and efficiency.

Contribution

It reveals the synergistic effect of water and quinone mediators in improving Li-O2 battery discharge and charge performance, a novel approach to addressing parasitic reactions and capacity limitations.

Findings

Water stabilizes quinone monoanion and dianion, shifting reduction potentials positively.

Water promotes larger Li2O2 crystal growth, up to 30 μm.

Enhanced discharge voltage, rate, and capacity with fewer side reactions.

Abstract

The parasitic reactions associated with reduced oxygen species and the difficulty in achieving the high theoretical capacity have been major issues plaguing development of practical non-aqueous Li-O2 batteries. We hereby address the above issues by exploring the synergistic effect of 2,5-di-tert-butyl-1,4- benzoquinone and H2O on the oxygen chemistry in a non-aqueous Li-O2 battery. Water stabilizes the quinone monoanion and dianion, shifting the reduction potentials of the quinone and monoanion to more positive values (vs. Li+). When water and the quinone are used together in a (largely) non-aqueous Li-O2 battery, the cell discharge operates via a two-electron oxygen reduction reaction to form Li2O2, the battery discharge voltage, rate, capacity all being considerably increased and fewer side reactions being detected; Li2O2 crystals can grow up to 30 um, more than an order of magnitude larger than cases with the quinone alone or without any additives, suggesting that water is essential to promoting a solution dominated process with the quinone on discharging. The catalytic reduction of O2 by the quinone monoanion is predominantly responsible for the attractive features mentioned above. Water stabilizes the quinone monoanion via hydrogen bond formation and by coordination of the Li+ ions, and it also helps increase the solvation, concentration, life time and diffusion length of reduced oxygen species that dictate the discharge voltage, rate and capacity of the battery. When a redox mediator is also used to aid the charging process, a high-power, high energy- density, rechargeable Li-O2 battery is obtained.