Strong spatial and spectral localization of surface plasmons in individual randomly disordered gold nanosponges

TL;DR

This study demonstrates that individual gold nanosponges exhibit highly localized surface plasmon modes with high quality factors, confirmed through near-field spectroscopy, highlighting their potential for advanced optical applications.

Contribution

The paper provides direct experimental evidence of spatially and spectrally confined plasmonic hot-spots in individual gold nanosponges using near-field spectroscopy.

Findings

Localization lengths of 10 nm for plasmon modes

High quality factors exceeding 40 for hot-spots

Strong localization regime confirmed by statistical analysis

Abstract

Porous nanosponges, percolated with a three-dimensional network of 10-nm sized ligaments, recently emerged as promising substrates for plasmon-enhanced spectroscopy and (photo-)catalysis. Experimental and theoretical work suggests surface plasmon localization in some hot-spot modes as the physical origin of their unusual optical properties, but so far the existence of such hot-spots has not been proven. Here we use scattering-type scanning near-field nano-spectroscopy on individual gold nanosponges to reveal spatially and spectrally confined modes with 10 nanometer localization lengths by mapping the local optical density of states. High quality factors of individual hot-spots of more than 40 are demonstrated. A statistical analysis of near-field intensity fluctuations unveils plasmonics in the strong localization regime. The observed field localization and enhancement make such nanosponges an appealing platform for a variety of applications ranging from nonlinear optics to strong-coupling physics.