Electric field distortions in structures of the twist bend nematic (NTB) phase of a bent-core liquid crystal

TL;DR

This study uses dielectric spectroscopy to analyze how electric fields distort the helicoidal structure of the twist bend nematic phase in a bent-core liquid crystal, revealing collective relaxation processes and phase transition behaviors.

Contribution

It provides experimental evidence of electric field-induced distortions and phase transitions in the twist bend nematic phase, supporting current theoretical models.

Findings

Identification of two collective relaxation processes.

Observation of a phase transition from twist bend to splay bend structure.

Demonstration of electric field effects on the helicoidal angle and wave vector.

Abstract

Dielectric spectroscopy of a twist bend nematic phase of an achiral bent core liquid crystalline compound under DC bias is used to investigate its response to electric field. Two collective relaxation processes are revealed, these are assigned to distortions of helicoidal structure by the external bias field. Frequency of the mode depends primarily on the helicoidal angle and has anomalous, softening- like behaviour at the nematic to the twist bend nematic transition. A coupling of dielectric anisotropy with electric field gives rise to a new equilibrium periodic structure in the time scale involved. The modulus of the wave vector gradually vanishes on increasing the bias field (except for the initial behaviour, which is just the opposite). Transition from the twist bend to the splay bend structure is clearly observed by a sudden drop in the frequency of this mode, which decreases almost linearly with increasing field. Results agree with predictions from current models for the periodically distorted a twist bend nematic phase.