New places and phases of CO-poor/CI-rich molecular gas in the Universe
Padelis P. Papadopoulos, Thomas G. Bisbas, and Zhiyu Zhang

TL;DR
This paper explores how cosmic rays influence the chemical composition of molecular gas in the universe, leading to CO-poor/CI-rich phases in various astrophysical environments, and discusses observational strategies to detect this gas.
Contribution
It demonstrates that cosmic rays can induce a widespread CO-poor/CI-rich molecular gas phase in diverse cosmic settings, expanding understanding of molecular gas chemistry.
Findings
CRs can make molecular gas CO-invisible in star-forming galaxies.
High-resolution imaging of atomic carbon lines can reveal CO-poor/CI-rich gas.
New observational facilities can detect this phase in different cosmic environments.
Abstract
In this work we extend the work on the recently discovered role of Cosmic Rays (CRs) in regulating the average CO/ abundance ratio in molecular clouds (and thus their CO line visibility) in starburst galaxies, and find that it can lead to a CO-poor/CI-rich gas phase even in environments with Galactic or in only modestly enhanced CR backgrounds expected in ordinary star-forming galaxies. Furthermore, the same CR-driven astro-chemistry raises the possibility of a widespread phase transition of molecular gas towards a CO-poor/CI-rich phase in: a) molecular gas outflows found in star-forming galaxies, b) active galactic nuclei (AGNs), and c) near synchrotron-emitting radio jets and the radio-loud cores of powerful radio galaxies. For main sequence galaxies we find that CRs can render some of their molecular gas mass CO-invisible, compounding the effects of low…
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