Path-averaged Kinetic Equation for Stochastic Systems
De-yu Zhong, Guang-qian Wang, Tie-jian Li, Ming-xi ZHANG, You Xia, and, Yu Zhang

TL;DR
This paper introduces a new kinetic equation for stochastic systems that accounts for path-dependence by using a path density operator, extending traditional models like the Fokker-Planck equation to non-Markovian, large-scale systems.
Contribution
The paper derives a path-averaged kinetic equation incorporating cumulants of transition paths, capturing non-local and long-time correlation effects in stochastic systems.
Findings
Derivation of a new path-dependent kinetic equation
Equivalence of cumulants and jump moments in short-time limit
Extension of Fokker-Planck framework to non-Markovian systems
Abstract
For a stochastic system, its evolution from one state to another can have a large number of possible paths. Non-uniformity in the field of system variables leads the local dynamics in state transition varies considerably from path to path and thus the distribution of the paths affects statistical characteristics of the system. Such a characteristic can be referred to as path-dependence of a system, and long-time correlation is an intrinsic feature of path-dependence systems. We employed a local path density operator to describe the distribution of state transition paths, and based on which we derived a new kinetic equation for path-dependent systems. The kinetic equation is similar in form to the Kramers-Moyal expansion, but with its expansion coefficients determined by the cumulants with respect to state transition paths, instead of transition moments. This characteristic makes it…
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Taxonomy
TopicsAdvanced Thermodynamics and Statistical Mechanics · Spectroscopy and Quantum Chemical Studies · stochastic dynamics and bifurcation
