Effects of external magnetic field and hydrostatic pressure on magnetic and structural phase transitions in Pr0.6Sr0.4MnO3

TL;DR

This study explores how external magnetic fields and hydrostatic pressure influence magnetic and structural phase transitions in Pr0.6Sr0.4MnO3, revealing pressure stabilizes the monoclinic phase while magnetic fields induce structural changes.

Contribution

It provides new insights into the effects of magnetic field and pressure on phase transitions in Pr0.6Sr0.4MnO3, highlighting the contrasting roles of these external stimuli.

Findings

Hydrostatic pressure shifts TS to higher temperatures by 27 K.

Magnetic field induces a structural transition from monoclinic to orthorhombic.

Pressure stabilizes the low-temperature monoclinic phase.

Abstract

We investigate the effect of hydrostatic pressure on temperature dependence of magnetization and also the influence of magnetic field on linear thermal expansion in polycrystalline Pr0.6Sr0.4MnO3, which is ferromagnetic at room temperature (TC = 305 K) but its magnetization undergoes an abrupt decrease at TS = 89 K within the ferromagnetic state. Normal and inverse magnetocaloric effects around TC and TS, respectively, were reported earlier in this single phase compound [D. V. M. Repaka et al., J. Appl. Phys. 112, 123915 (2012)]. The thermal expansion shows an abrupt decrease at TS in zero magnetic field but it transforms into an abrupt increase at the same temperature under 7 T, which we interpret as the consequence of magnetic field-induced structural transition from a low-volume monoclinic (I2/a symmetry) to a high volume orthorhombic (Pnma symmetry) phase in corroboration with a published neutron diffraction study in zero magnetic field. While the external magnetic field does not change TS, application of a hydrostatic pressure of P = 1.16 GPa shifts the magnetic anomaly at TS towards high temperature. The pressure induced shift of the low-temperature anomaly (deltaTS = 27 K) is nine-times more than that of the ferromagnetic Curie temperature (deltaTC = 3K). Our results suggest that while hydrostatic pressure stabilizes the low temperature monoclinic phase at the expense of orthorhombic phase, magnetic field has an opposite effect.