Photonics and Spectroscopy in Nanojunctions: A Theoretical Insight

TL;DR

This paper reviews recent theoretical advances in optical spectroscopy of nanojunctions, highlighting a unified approach that bridges nonlinear spectroscopy and quantum transport, with implications for optoelectronic applications.

Contribution

It presents a unified theoretical framework for optical response in nanojunctions, integrating nonlinear spectroscopy and quantum transport methods, especially emphasizing Green function techniques.

Findings

Unified theoretical description of nanojunction spectroscopy.

Green function methods are effective for classical radiation fields.

Differences in quantum radiation field treatments are significant.

Abstract

Progress of experimental techniques at nanoscale in the last decade made optical measurements in current-carrying nanojunctions a reality thus indicating emergence of a new field of research coined as optoelectronics. Optical spectroscopy of open nonequilibrium systems is a natural meeting point for (at least) two research areas: nonlinear optical spectroscopy and quantum transport, each with its own theoretical toolbox. We review recent progress in the field comparing theoretical treatments of optical response in nanojunctions as is accepted in nonlinear spectroscopy and quantum transport communities. A unified theoretical description of spectroscopy in nanojunctions is presented. We argue that theoretical approaches of the quantum transport community (and in particular, the Green function based considerations) yield a convenient tool for optoelectronics when radiation field is treated classically, and that differences between the toolboxes may become critical when studying quantum radiation field in junctions.