Collective dissolution of microbubbles

TL;DR

This paper develops theoretical models to understand how neighboring microbubbles slow down their dissolution through diffusive shielding, revealing complex spatial and dimensional effects on dissolution dynamics.

Contribution

It introduces new analytical frameworks for modeling diffusive shielding in microbubble lattices, including exact, reflection, and continuum approaches, and analyzes their impact on dissolution times.

Findings

Diffusive shielding significantly prolongs bubble dissolution times.

Dissolution front propagates inward from lattice edges.

Dissolution time scales logarithmically or algebraically with bubble number depending on dimension.

Abstract

A microscopic bubble of soluble gas always dissolves in finite time in an under-saturated fluid. This diffusive process is driven by the difference between the gas concentration near the bubble, whose value is governed by the internal pressure through Henry's law, and the concentration in the far field. The presence of neighbouring bubbles can significantly slow down this process by increasing the effective background concentration and reducing the diffusing flux of dissolved gas experienced by each bubble. We develop theoretical modelling of such diffusive shielding process in the case of small microbubbles whose internal pressure is dominated by Laplace pressure. We first use an exact semi-analytical solution to capture the case of two bubbles, analyse in detail the shielding effect and show that hydrodynamic effects are mostly negligible except in the case of almost-touching bubbles. In order to tackle the case of multiple bubbles, we then derive and validate two analytical approximate yet generic frameworks, first using the method of reflections and then by proposing a self-consistent continuum description. Using both modelling frameworks, we examine the dissolution of regular 1D, 2D and 3D bubble lattices. Bubbles located at the edge of the lattices dissolve first, while innermost bubbles benefit from the diffusive shielding effect, leading to the inward propagation of a dissolution front within the lattice. We show that diffusive shielding leads to severalfold increases in the dissolution time which grows logarithmically with the number of bubbles in 1D-lattices and algebraically in two and three dimensions, scaling respectively as its square root and 2/3-power. We further illustrate the sensitivity of the dissolution patterns to initial fluctuations in bubble size or arrangement in the case of large and dense lattices, as well as non-intuitive oscillatory effects.