Graphene functionalised by laser ablated V2O5 as highly sensitive NH3 sensor

TL;DR

This study demonstrates that laser-ablated V2O5 functionalization significantly enhances the ammonia sensing capabilities of graphene at room temperature, improving response time, sensitivity, and reversibility.

Contribution

It introduces a novel laser ablation method to functionalize graphene with V2O5, leading to improved gas sensor performance compared to unmodified graphene.

Findings

Enhanced ammonia detection sensitivity and response time.

Increased surface adsorption sites due to V2O5 deposition.

Induction of defects in graphene improves sensor performance.

Abstract

Graphene has been recognized as a promising gas sensing material. The response of graphene-based sensors can be radically improved by introducing defects in graphene using, e. g., metal or metal oxide nanoparticles. We have functionalised CVD grown, single layer graphene by applying pulsed laser deposition (PLD) of V2O5 which resulted in a thin V2O5 layer on graphene with average thickness of ~0.6 nm. According to Raman analysis, PLD process also induced defects in graphene. Compared to unmodified graphene, the obtained chemiresistive sensor showed considerable improvement of sensing ammonia at room temperature. In addition, also the response time, sensitivity and reversibility were essentially enhanced due to graphene functionalisation by laser deposited V2O5. This can be explained by increased surface density of gas adsorption sites introduced by high energy atoms in laser ablation plasma and formation of nanophase boundaries between deposited V2O5 and graphene.