Boundary flow of viscoelastic polyelectrolyte solutions

TL;DR

This study investigates the boundary flow behavior of viscoelastic polyelectrolyte solutions confined between platinum surfaces, revealing a charge-induced adsorbed layer and a distinct low-viscosity boundary layer that influences flow at nanoscales.

Contribution

It provides a detailed experimental analysis of boundary slip and interfacial properties of polyelectrolyte solutions, introducing a quantitative description based on interfacial friction rather than slip length.

Findings

Flow at larger distances follows a partial slip boundary condition.

Wall slip is quantitatively described by an interfacial friction coefficient.

A low viscosity boundary layer is identified, with fixed thickness and viscosity.

Abstract

We report an investigation of the equilibrium and dynamic properties of polyelectrolyte solutions confined between platinum surfaces with a dynamic Surface Force Apparatus. The polyelectrolyte adsorbs on the surfaces in a dense compact layer bearing a surface charge in good agreement with the theoretical predictions. The flow of the solution on this charged adsorbed layer is probed over four decades of spatial scales and one decade of frequency by dynamic measurements. At distances larger than the hundredth of nanometers, the flow of the viscoelastic solution is well described by a partial slip boundary condition. We show that the wall slip is quantitatively described by an interfacial friction coefficient, according to the original Navier's formulation, and not by a slip length. At smaller distance the partial slip model overestimates the solution mobility, and we observe the presence of a low viscosity layer coating the surfaces. The viscosity and thickness of this boundary layer are directly resolved, and found to be independent on shear-rate, frequency, and confinement. We discuss the thickness of the low viscosity layer in terms of the structural length of the semi-dilute solution and the Debye length screening the adsorbed layer charge.